Uranium(IV) complexes of calix[n] arenes (n=4, 6 and 8)

被引：24

作者：

Salmon, L ^{[1
]}

Thuéry, P ^{[1
]}

Ephritikhine, M ^{[1
]}

机构：

[1] CEA Saclay, CNRS, DRECAM, DSM,URA 331,Serv Chim Mol, F-91191 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 08期

关键词：

D O I：

10.1039/b516438a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of UCl4 with calix[n]arenes (n = 4, 6 and 8) in THF or pyridine gave the mononuclear [UCl2(calix[4]arene - 2H)- THF)(2)], bis-binuclear [U2Cl2(calix[6]arene - 6H)(THF)(3)](2) and trinuclear [Hpy](6)[U3Cl11(calix[8]arene - 7H)] complexes, respectively, which are the first U-IV complexes of O-unsubstituted calixarenes.

引用

页码：856 / 858

页数：3

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