Magnetic Cooling at a Single Molecule Level: a Spectroscopic Investigation of Isolated Molecules on a Surface

被引：29

作者：

Corradini, Valdis ^{[1
]}

Ghirri, Alberto ^{[1
]}

Candini, Andrea ^{[1
]}

Biagi, Roberto ^{[1
,5
]}

del Pennino, Umberto ^{[1
,5
]}

Dotti, Gianluca ^{[5
]}

Otero, Edwige ^{[2
]}

Choueikani, Fadi ^{[2
]}

Blagg, Robin J. ^{[3
,4
]}

McInnes, Eric J. L. ^{[3
,4
]}

Affronte, Marco ^{[1
,5
]}

机构：

[1] CNR, Inst Nanosci, Ctr S3, I-41125 Modena, Italy

[2] Synchrotron SOLEIL, LOrme Merisiers, F-91120 St Aubin, France

[3] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[4] Univ Manchester, Photon Sci Inst, Manchester M13 9PL, Lancs, England

[5] Univ Modena & Reggio Emilia, Dipartimento Sci Fis Informat & Matemat, I-41125 Modena, Italy

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

molecular nanomagnets; magnetocaloric effect; x-ray magnetic circular dichroism; surface deposition; FE-III; DICHROISM; ANISOTROPY; GRAPHITE; CLUSTERS; RINGS;

D O I：

10.1002/adma.201205257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sub-monolayer distribution of isolated molecular Fe-14(bta)(6) nanomagnets is deposited intact on a Au(111) surface and investigated by X-ray magnetic circular dichroism spectroscopy. The entropy variation with respect to the applied magnetic field is extracted from the magnetization curves and evidences high magnetocaloric values at the single molecule level.

引用

页码：2816 / 2820

页数：5

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