Determination of the initiation rate in the polymerization of zinc, cobalt and nickel acrylates

被引：4

作者：

Czerniawski, T

Wojtczak, Z

机构：

[1] N. Copernicus University, Faculty of Chemistry

来源：

EUROPEAN POLYMER JOURNAL | 1996年 / 32卷 / 08期

关键词：

D O I：

10.1016/0014-3057(96)00031-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Results for the determination of the initiation rate of polymerization reaction of zinc, cobalt and nickel acrylates, initiated by 2,2'-azobisisobutyronitryle in dimethylformamide at different temperatures are reported. The inhibition method involving the stable radical N,N-diphenyl-N'-picrylhydrazyl has been used. The initiation rate constants 2k(d)f and activation energy of initiation E(2kdf) have been determined. Copyright (C) 1996 Published by Elsevier Science Ltd.

引用

页码：1035 / 1036

页数：2

共 8 条

[1]

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[2]

BARLETT P, 1950, J AM CHEM SOC, V72, P1051

[3]

BRAKSAND G, 1974, J POLYM SCI POL LETT, V12, P399

[4] THE INHIBITED COPOLYMERIZATION OF ACRYLONITRILE WITH ZINC ACRYLATE IN DIMETHYLFORMAMIDE SOLUTION [J].