The reaction of 2-bromopyridine with a PH3/H2 system in the KOH/DMSO suspension: A short route to tris(2-pyridyl)phosphine

被引：7
作者：
Trofimov, Boris A. [1 ]
Gusarova, Nina K. [1 ]
Artem'ev, Alexander V. [1 ]
Malysheva, Svetlana F. [1 ]
Belogorlova, Nataliya A. [1 ]
Korocheva, Anastasiya O. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia
来源：
HETEROATOM CHEMISTRY | 2012年 / 23卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
COMPLEXES; PHOSPHINE; BIDENTATE; CATALYSTS; CHEMISTRY; PYRIDYL; ENCAPSULATION; MONODENTATE; LIGANDS;
D O I：
10.1002/hc.21030
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The straightforward reaction of 2-bromopyridine with a PH3/H2 system (generated from phosphorus red and aqueous alkali) in the superbasic KOH/DMSO/(H2O) suspension under mild conditions (70 degrees C, 1.5 h, atmospheric pressure) affords selectively and cleanly tris(2-pyridyl)phosphine in 50% yield; no admixtures of the expected primary and secondary pyridylphosphines were observed in the crude product. (c) 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:411414, 2012; View this article online at . DOI 10.1002/hc.21030
引用
收藏
页码：411 / 414
页数：4
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