Versatile ''3+1'' syntheses of acenaphthoporphyrins, a new family of highly conjugated tetrapyrroles

被引:52
作者
Chandrasekar, P [1 ]
Lash, TD [1 ]
机构
[1] ILLINOIS STATE UNIV,DEPT CHEM,NORMAL,IL 61790
基金
美国国家科学基金会;
关键词
D O I
10.1016/0040-4039(96)00998-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Acenaphthoporphyrins, a new group of porphyrins with strongly red shifted electronic absorption spectra, have been prepared by the acid catalysed condensation of a pyrrole-2,5-dicarboxaldehyde with acenaphthotripyrranes: similarly, c-annelated pyrroledialdehydes afforded the related opp-diacenaphthoporphyrins and a mixed porphyrin system with fused phenanthrene and acenaphthylene rings. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:4873 / 4876
页数:4
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