Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

被引：27

作者：

Lamani, Manjunath ^{[1
]}

Guralamata, Ravikumara Siddappa ^{[1
]}

Prabhu, Kandikere Ramaiah ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 52期

关键词：

DOUBLE-BOND MIGRATION; ASYMMETRIC-SYNTHESIS; RACEMIZATION; OXIDATIONS; CHEMISTRY; TARTRATE; DIIMIDE; ACID;

D O I：

10.1039/c2cc32611f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient aerobic reduction of olefins, internal as well as terminal, is developed using guanidine as an organocatalyst. A remarkable chemoselectivity in reduction has been demonstrated in the presence of a variety of functional groups and protective groups and a selective reduction of a terminal olefin in the presence of an internal olefin is revealed.

引用

页码：6583 / 6585

页数：3

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