AN IMPROVED PROCEDURE FOR OXIDATION OF ALCOHOLS TO ALDEHYDES AND KETONES WITH MANGANESE DIOXIDE SUPPORTED ON GRAPHITE UNDER SOLVENT-FREE CONDITIONS

被引：0

作者：

Lou, Ji-Dong ^{[1
,2
]}

Lin, Fang ^{[1
]}

Zhang, Changhe ^{[3
]}

Zhu, Li-Yun ^{[1
]}

Lin, Jianan ^{[1
]}

机构：

[1] China Jiliang Univ, Coll Life Sci, Hangzhou 310018, Peoples R China

[2] Sirnaomics Inc, Gaithersburg, MD 20879 USA

[3] Univ Tras Os Montes & Alto Douro UTAD, Ctr Res & Technol Agroenvironm & Biol Sci CITAB, Dept Biol & Environm, P-5001801 Vila Real, Portugal

来源：

OXIDATION COMMUNICATIONS | 2013年 / 36卷 / 02期

关键词：

alcohols; aldehydes; graphite; ketones; manganese dioxide; oxidation; solvent-free; HETEROGENEOUS CONDITIONS; ORGANIC-SYNTHESIS; EFFICIENT OXIDATION; ALUMINUM SILICATE; KIESELGUHR; BENZOINS; REAGENT; CHEMISTRY;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and selective procedure for oxidation of alcohols to the corresponding aldehydes and ketones using manganese dioxide supported on graphite at around 50 degrees C under solvent-free conditions and grind in the yields between 80 and 92% is described. This method offers several advantages, such as short reaction times, high yields of the products, and a non-toxic and inexpensive reagent, which make the oxidation process convenient, economic, and environmentally benign.

引用

页码：486 / 491

页数：6

共 22 条

[1]

FATIADI AJ, 1976, SYNTHESIS-STUTTGART, P65

[2] ACTIVE MANGANESE-DIOXIDE OXIDATION IN ORGANIC-CHEMISTRY .2. [J].

FATIADI, AJ .

SYNTHESIS-STUTTGART, 1976, (03) :133-167

[3]

Fieser L., 1967, Reagents for Organic Synthesis, V1-20

[4]

Freeman F., 1986, ORGANIC SYNTHESIS OX, P68

[5]

Haines A. H, 1988, METHODS OXIDATION OR, V17

[6] MANGANESE DIOXIDE SUPPORTED ON ALUMINUM SILICATE: A NEW REAGENT FOR OXIDATION OF ALCOHOLS UNDER HETEROGENEOUS CONDITIONS [J].

Huang, Li-Hong ;

Ma, Yi-Chun ;

Zhang, Changhe ;

Wang, Qiang ;

Zou, Xiao-Nan ;

Lou, Ji-Dong .

SYNTHETIC COMMUNICATIONS, 2012, 42 (22) :3377-3382

[7] New Reagent, Manganese Dioxide Supported on Kieselguhr, for Effective Oxidation of Benzoins [J].

Huang, Li-Hong ;

Wang, Qiang ;

Ma, Yi-Chun ;

Lou, Ji-Dong ;

Zhang, Changhe .

SYNTHETIC COMMUNICATIONS, 2011, 41 (11) :1682-1687

[8]

Laszlo P., 1987, Preparative Chemistry Using Supported Reagents

[9]

Ley S.V., 1991, COMPREHENSIVE ORGANI, V7, P251, DOI DOI 10.1016/B978-0-08-052349-1.09002-8

[10] Solvent free oxidation of alcohols with manganese dioxide [J].

Lou, JD ;

Xu, ZN .

TETRAHEDRON LETTERS, 2002, 43 (35) :6149-6150

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