catena-Poly[[[triaquacadmium(II)]-μ-3-carboxylatophenoxyacetato-κ3O3,O3′:O"] sesquihydrate]

被引：1

作者：

Gao, S

Ng, SW ^{[1
]}

机构：

[1] Heilongjiang Univ, Coll Chem & Mat Sci, Harbin 150080, Peoples R China

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

D O I：

10.1107/S160053680503850X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The dicarboxylate ligand in the title compound, [Cd(C9H6O5)(H2O) (3)]center dot 1.5H(2)O, bridges triaquacadmium groups into a linear chain; the carboxylate arm that is directly connected to the aromatic ring behaves as a chelate, whereas the carboxylate arm of the oxyacetate portion binds in a monodentate mode. The octahedral environment of cadmium is distorted towards a pentagonal bipyramid, owing to a long Cd center dot center dot center dot O interaction of 2.721 (2) angstrom.

引用

页码：M179 / M180

页数：2