Metal-free hydrogenation catalysis of polycyclic aromatic hydrocarbons

被引：109

作者：

Segawa, Yasutomo ^{[2
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S3H6, Canada

[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 98期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FRUSTRATED LEWIS PAIRS; SELECTIVE HYDROGENATION; ORGANIC-SYNTHESIS; DIESEL EXHAUST; ACTIVATION; REDUCTION; DENSITY; IMINES; ACENES;

D O I：

10.1039/c2cc37190a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The frustrated Lewis pair, B(C6F5)(3)/Ph2PC6F5, acts as an efficient catalyst for the hydrogenation of the polycyclic hydrocarbons including anthracene derivatives, tetracene and tetraphene, at 80 degrees C and 100 atm H-2 pressure via a mechanism involving protonation of polyaromatic species followed by hydride transfer.

引用

页码：11963 / 11965

页数：3

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