Hydrocarboxylation of terminal alkenes in supercritical carbon dioxide

被引：15

作者：

Estorach, Clara Tortosa ^{[1
]}

Orejon, Arantxa ^{[1
]}

Ruiz, Nuria ^{[1
]}

Masdeu-Bulto, Anna M. ^{[1
]}

Laurenczy, Gabor ^{[2
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain

[2] Ecole Polytech Fed Lausanne, Lab Med & Organomet Chem, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 22卷 / 22期

关键词：

hydrocarboxylation; hydroxycarbonylation; palladium; supercritical fluids;

D O I：

10.1002/ejic.200800282

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic hydrocarboxylation of linear alkenes to carboxylic acids using supercritical carbon dioxide as a solvent was studied. High selectivities in acids have been obtained. The best results were achieved when adding a perfluorinated surfactant to the reaction mixture (93%, conversions and ca. 80% selectivity). Comparative multinuclear high-pressure NMR spectroscopic studies in [D-8]THF and in supercritical CO2 show the formation of Pd-0 species. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：3524 / 3531

页数：8

共 57 条

[1]

Ali B.E., 1993, J MOL CATAL, V80, P377

[2] Formation of anionic palladium(0) complexes ligated by the trifluoroacetate ion and their reactivity in oxidative addition [J].

Amatore, C ;

Jutand, A ;

Lemaître, F ;

Ricard, JL ;

Kozuch, S ;

Shaik, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (23) :3728-3734

[3] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[4]

Anastas PT., 1998, Principles of green chemistry

[5]

[Anonymous], NEW SYNTHESIS CARBON

[6]

[Anonymous], 1999, CHEM SYNTHESIS USING

[7] Carbonylation reactions 7. Regioselective synthesis of 2-arylpropionic acids by catalytic carbonylation of styrene derivatives in the presence of palladium compounds: the critical role of the counter anion [J].

Bonnet, MC ;

Monteiro, AL ;

Tkatchenko, I .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) :131-136

[8] Water in supercritical carbon dioxide microemulsions: Spectroscopic investigation of a new environment for aqueous inorganic chemistry [J].

Clarke, MJ ;

Harrison, KL ;

Johnston, KP ;

Howdle, SM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (27) :6399-6406

[9] The electron-poorphosphines P{C6H3(CF3)2-3,5}3 and P(C6F5)3 do not mimic phosphites as ligands for hydroformylation.: A comparison of the coordination chemistry of P{C6H3(CF3)2-3,5}3 and P(C6F5)3 and the unexpectedly low hydroformylation activity of their rhodium complexes [J].

Clarke, ML ;

Ellis, D ;

Mason, KL ;

Orpen, AG ;

Pringle, PG ;

Wingad, RL ;

Zaher, DA ;

Baker, RT .

DALTON TRANSACTIONS, 2005, (07) :1294-1300

[10] Homogeneous catalysis - new approaches to catalyst separation, recovery, and recycling [J].

Cole-Hamilton, DJ .

SCIENCE, 2003, 299 (5613) :1702-1706

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