Azo dyes featuring with nitrobenzoxadiazole (NBD) unit: A new selective chromogenic and fluorogenic sensor for cyanide ion

被引:209
作者
Tsui, Yao-Kang [1 ]
Devaraj, Soosai [1 ]
Yen, Yao-Pin [1 ]
机构
[1] Providence Univ, Dept Appl Chem, Taichung 433, Taiwan
关键词
Chromogenic sensor; Fluorogenic sensor; Cyanide ion; NBD-derivatives; Azodyes; COLORIMETRIC DETECTION; FLUORESCENT SENSORS; SENSING CYANIDE; RECOGNITION; CHEMODOSIMETER; HIGHLIGHTS; COMPLEX; REAGENT; ANIONS;
D O I
10.1016/j.snb.2011.10.069
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Three new chemodosimeters 1-3 were prepared, and their chromogenic and fluorogenic behaviors toward various anions were investigated. Receptors 1-3 show exclusive response toward CN- ion and also distinguish CN- from other anions by different color changes in aqueous solution (EtOH/H2O = 3/7, v/v). Among them, receptor 1 selectively exhibits a pronounced CN- -induced fluorescence enhancement. Thus, the receptor 1 can be used as a colorimetric and fluorescent sensor for the determination of CN- ion. The practical use of the receptor 1 for the determination of sodium cyanide (1.5 mu M) in aqueous solution was also reported. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:510 / 519
页数:10
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