Preparation of porous MoS2 via a sol-gel route using (NH4)2Mo3S13 as precursor

被引：23

作者：

Li, Ning ^{[1
]}

Chai, Yongming ^{[1
]}

Dong, Bin ^{[1
]}

Liu, Bin ^{[2
]}

Guo, Hailing ^{[1
]}

Liu, Chenguang ^{[1
,2
]}

机构：

[1] China Univ Petr E China, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China

[2] China Univ Petr E China, CNPC, Key Lab Catalysis, Qingdao 266580, Peoples R China

来源：

MATERIALS LETTERS | 2012年 / 88卷

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

Sol-gel; MoS2; Ethanol supercritical drying; Porous material; Nanoparticles; CATALYSTS; HYDRODESULFURIZATION; THIOMOLYBDATES; AEROGELS; POWDERS;

D O I：

10.1016/j.matlet.2012.08.031

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

High-surface-area porous MoS2 was successfully synthesized through a sol-gel route using (NH4)(2)Mo3S13 as precursor. A novel molybdenum polysulfide gel "Mo3S12" was firstly prepared through the reaction of (NH4)(2)Mo3S13 formamide solution with hydrochloric acid solution. Subsequently, the porous MoS2 was obtained from the "Mo3S12" gel by ethanol supercritical drying technique. X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), nitrogen physisorption measurement (BET) were used to characterize the porous MoS2 samples. The results indicated this porous MoS2 has a broad range of pore sizes and a BET surface area of 315 m(2)/g and a pore volume of 1.9 cm(3)/g. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：112 / 115

页数：4

共 18 条

[1] The influence of reducing and sulfiding conditions on the properties of unsupported MoS2-based catalysts [J].

Afanasiev, Pavel .

JOURNAL OF CATALYSIS, 2010, 269 (02) :269-280

[2] Characterization and HDS activity of mesoporous MoS2 catalysts prepared by in situ activation of tetraalkylammonium thiomolybdates [J].

Alonso, G ;

Berhault, G ;

Aguilar, A ;

Collins, V ;

Ornelas, C ;

Fuentes, S ;

Chianelli, RR .

JOURNAL OF CATALYSIS, 2002, 208 (02) :359-369

[3]

Bag S, 2009, NAT CHEM, V1, P217, DOI [10.1038/NCHEM.208, 10.1038/nchem.208]

[4] Preparation and structural characterization of nano-sized amorphous powders of MoS2 by γ-irradiation method [J].

Chu, GS ;

Bian, GZ ;

Fu, YL ;

Zhang, ZC .

MATERIALS LETTERS, 2000, 43 (03) :81-86

[5] An in situ structural study of the thermal decomposition reactions of the ammonium thiomolybdates, (NH4)2Mo2S12•2H2O and (NH4)2Mo3S13•2H2O [J].

Hibble, SJ ;

Feaviour, MR .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (10) :2607-2614

[6] Synthesis and characterization of germanium sulfide aerogels [J].

Kalebaila, KK ;

Georgiev, DG ;

Brock, SL .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2006, 352 (03) :232-240

[7] Electrochemical lithiation/delithiation performances of 3D flowerlike MoS2 powders prepared by ionic liquid assisted hydrothermal route [J].

Li, Hui ;

Li, Weijun ;

Ma, Lin ;

Chen, Weixiang ;

Wang, Jianming .

JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 471 (1-2) :442-447

[8]

Mohanan JL, 2005, SCIENCE, V307, P397, DOI 10.1126/science.1106525

[9] DIRECTED SYNTHESIS OF [MO3S13]2-, AN ISOLATED CLUSTER CONTAINING SULFUR-ATOMS IN 3 DIFFERENT STATES OF BONDING [J].

MULLER, A ;

SARKAR, S ;

BHATTACHARYYA, RG ;

POHL, S ;

DARTMANN, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (07) :535-535

[10] Extraordinary Selectivity of CoMo3S13 Chalcogel for C2H6 and CO2 Adsorption [J].

Shafaei-Fallah, Maryam ;

Rothenberger, Alexander ;

Katsoulidis, Alexandros P. ;

He, Jiaqing ;

Malliakas, Christos D. ;

Kanatzidis, Mercouri G. .

ADVANCED MATERIALS, 2011, 23 (42) :4857-4860

← 1 2 →