Electrochemical impedance spectroscopy of Li4Ti5O12 and LiCoO2 based half-cells and Li4Ti5O12/LiCoO2 cells: Internal interfaces and influence of state-of-charge and cycle number

被引：29

作者：

Schweikert, Nina ^{[1
]}

Heinzmann, Ralf ^{[1
]}

Eichhoefer, Andreas ^{[1
]}

Hahn, Horst ^{[1
,2
]}

Indris, Sylvio ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[2] Tech Univ Darmstadt, KIT TUD Joint Res Lab Nanomat, D-64287 Darmstadt, Germany

来源：

SOLID STATE IONICS | 2012年 / 226卷

关键词：

Lithium-ion batteries; Electrochemical impedance spectroscopy; State-of-charge; State-of-health; LITHIUM-ION BATTERIES; AC-IMPEDANCE; SECONDARY BATTERIES; ELECTRODES; INTERCALATION; INSERTION; SPINEL; CATHODES; SPECTRA; DIFFRACTION;

D O I：

10.1016/j.ssi.2012.08.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We studied Li/Li4Ti5O12 and Li/LiCoO2 half-cells as well as Li4Ti5O12/LiCoO2 coin-type battery cells at different state-of-charge over several cycles by means of electrochemical impedance spectroscopy. A simple equivalent-circuit model has been applied to probe changes at the internal interfaces of these batteries. The parameters of this model are used to follow the state-of-charge and state-of-health of the cells. Moreover plain empirical relations were introduced to accurately delineate those courses. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：15 / 23

页数：9

共 48 条

[1] Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. II: Modelling
Andre, D.
Meiler, M.
Steiner, K.
Walz, H.
Soczka-Guth, T.
Sauer, D. U.
[J]. JOURNAL OF POWER SOURCES, 2011, 196 (12) : 5349 - 5356
[2] Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. I. Experimental investigation
Andre, D.
Meiler, M.
Steiner, K.
Wimmer, Ch
Soczka-Guth, T.
Sauer, D. U.
[J]. JOURNAL OF POWER SOURCES, 2011, 196 (12) : 5334 - 5341
[3] LiCoO2:: formation, structure, lithium and oxygen nonstoichiometry, electrochemical behaviour and transport properties
Antolini, E
[J]. SOLID STATE IONICS, 2004, 170 (3-4) : 159 - 171
[4] On the Interpretation of Measured Impedance Spectra of Insertion Cathodes for Lithium-Ion Batteries
Atebamba, Jean-Marcel
Moskon, Joze
Pejovnik, Stane
Gaberscek, Miran
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (11) : A1218 - A1228
[5] Common electroanalytical behavior of Li intercalation processes into graphite and transition metal oxides
Aurbach, D
Levi, MD
Levi, E
Teller, H
Markovsky, B
Salitra, G
Heider, U
Heider, L
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (09) : 3024 - 3034
[6] On the capacity fading of LiCoO2 intercalation electrodes:: the effect of cycling, storage, temperature, and surface film forming additives
Aurbach, D
Markovsky, B
Rodkin, A
Levi, E
Cohen, YS
Kim, HJ
Schmidt, M
[J]. ELECTROCHIMICA ACTA, 2002, 47 (27) : 4291 - 4306
[7] Kinetics of lithium intercalation into carbon anodes: in situ impedance investigation of thickness and potential dependence
Barsoukov, E
Kim, JH
Kim, JH
Yoon, CO
Lee, H
[J]. SOLID STATE IONICS, 1999, 116 (3-4) : 249 - 261
[8] Comparison of kinetic properties of LiCoO2 and LiTi0.05Mg0.05Ni0.7Co0.2O2 by impedance spectroscopy
Barsoukov, E
Kim, DH
Lee, HS
Lee, H
Yakovleva, M
Gao, Y
Engel, JF
[J]. SOLID STATE IONICS, 2003, 161 (1-2) : 19 - 29
[9] Universal battery parameterization to yield a non-linear equivalent circuit valid for battery simulation at arbitrary load
Barsoukov, E
Kim, JH
Yoon, CO
Lee, H
[J]. JOURNAL OF POWER SOURCES, 1999, 83 (1-2) : 61 - 70
[10] PRACTICAL APPLICATION OF THE KRAMERS-KRONIG TRANSFORMATION ON IMPEDANCE MEASUREMENTS IN SOLID-STATE ELECTROCHEMISTRY
BOUKAMP, BA
[J]. SOLID STATE IONICS, 1993, 62 (1-2) : 131 - 141

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