Highly efficient and selective oxidation of 5-hydroxymethylfurfural by molecular oxygen in the presence of Cu-MnO2 catalyst

被引：52

作者：

Tong, Xinli ^{[1
]}

Yu, Linhao ^{[1
]}

Chen, Hui ^{[1
]}

Zhuang, Xuli ^{[1
]}

Liao, Shengyun ^{[1
]}

Cui, Hongge ^{[1
]}

机构：

[1] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin Key Lab Organ Solar Cells & Photochem Con, Tianjin 300384, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 90卷

关键词：

Oxidation; 5-hydroxymethylfurfural; 2,5-diformylfuran; Manganese oxides; Biomass transformation; AEROBIC OXIDATION; 2,5-DIFORMYLFURAN; BIOMASS; CHEMICALS; PERFORMANCE; CONVERSION; ACID; HMF;

D O I：

10.1016/j.catcom.2016.11.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The selective oxidation of 5-hydroxymethylfurfural (HMF) to produce value-added chemicals is a hot topic in the utilization of biomass, in which the development of heterogeneous catalyst and the use of O-2 as terminal oxidant is desired. In this work, a series of metal ion-doped MnO2 materials are successfully prepared using liquid precipitation method, and employed as catalysts for the aerobic oxidation of HMF in the alcoholic solvents. As a result, it is found that 86.0% conversion of HMF and 96.1% selectivity of 2,5-diformylfuran (DFF) was obtained under suitable conditions. Moreover, the Cu-MnO2 catalyst can keep a high activity after being recycled five times. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：91 / 94

页数：4

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