In Situ Obtained Cu(II) Compound with Coexistence of Polycatenation and Polythreading

被引：44

作者：

Cao, Xin-Yi ^{[1
,2
]}

Lin, Qi-Pu ^{[1
]}

Qin, Ye-Yan ^{[1
]}

Zhang, Jian ^{[1
]}

Li, Zhao-Ji ^{[1
]}

Cheng, Jian-Kai ^{[1
]}

Yao, Yuan-Gen ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Stale Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 01期

关键词：

UNPRECEDENTED INTERPENETRATING STRUCTURE; COORDINATION POLYMERS; MOLECULAR LADDERS; 3-DIMENSIONAL NETWORK; STRUCTURAL MOTIFS; FLEXIBLE LIGANDS; BUILDING-BLOCKS; CRYSTAL; LAYERS; ENTANGLEMENT;

D O I：

10.1021/cg800938y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present study describes the preparation and characterization of the first example of metal-organic frameworks (MOFs) with the coexistence of polycatenation and polythreading involving chemically and structurally different two-dimensional square grids [Cu(II)(2)(5-HIPA)(2)(4,4'-bipy)(2)(H2O)(2)](n), (A, 5-HIPA = 5-hydroxyisophthalato) and irregular layers [Cu(II)(3)(5-HIPA)(2)(2-PyC)(2)(4,4'-bipy)(2)(H2O)(4)](n) (B) in a unique three-dimensional framework [(A)(B)] center dot 6.5nH(2)O (1) with the in situ generated pyridine-2-carboxylate (2-PyC) ligand.

引用

页码：20 / 23

页数：4

共 53 条

[1] Using long bis(4-pyridyl) ligands designed for the self-assembly of coordination frameworks and architectures [J].