Kinetics and Thermodynamics of the Formation of Compounds of Calcium Ions and Amino Acids: Their Structure and Stability

被引:12
作者
Golovanova, O. A. [1 ]
Tomashevsky, I. A. [1 ]
机构
[1] Omsk State Univ, Omsk 644053, Russia
关键词
complexation; amino acids; thermodynamics; stability of complexes; potentiometry; kinetics of formation; COMPLEX-FORMATION; METAL-IONS; CRYSTALLIZATION; HISTIDINE; FEATURES; OXALATE; LIGAND; MODEL;
D O I
10.1134/S0036024419010084
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermodynamic constants of the stability of coordination compounds and their thermodynamic potentials of complexation in water solutions at 298 K are determined. Kinetic characteristics of the complexation reaction between calcium ions and amino acids in water solutions at 298 K are calculated. The ability of calcium ions to coordinate different amino acids as ligands is shown, and a tendency in the complexation of amino acids with different structures is established. Coordination compounds are studied via potentiometric titration using mathematical means of treating data.
引用
收藏
页码:7 / 17
页数:11
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