Fluidized ion exchange (FIX) to control NOM fouling in ultrafiltration

被引:39
作者
Cornelissen, E. R. [1 ]
Beerendonk, E. F. [1 ]
Nederlof, M. N. [2 ]
van der Hoek, J. P. [3 ]
Wessels, L. P. [1 ]
机构
[1] Kiwa Water Res, NL-3430 BB Nieuwegein, Netherlands
[2] Vitens, NL-8901 BE Leeuwarden, Netherlands
[3] Waternet, NL-1096 BA Amsterdam, Netherlands
关键词
Fluidized ion exchange (FIX); NOM fouling; Ultrafiltration; Calcium removal; NOM removal; NATURAL ORGANIC-MATTER; NANOFILTRATION MEMBRANES; REMOVAL; WATER;
D O I
10.1016/j.desal.2007.10.084
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
To control NOM fouling, either NOM or hardness ions can be (partly) removed before membrane filtration. In this work, anion Fluidized Ion Exchange (FIX) is used to remove NOM from untreated surface water and cation FIX is used to remove calcium and magnesium ions from untreated surface water. The effect of calcium and magnesium removal by cation FIX is studied in lab-scale ultrafiltration (UF). FIX was successful in treating untreated surface water containing high loads Of Suspended solids (33 mg/L). No problems have been observed with clogging of the resin bed during operation. NOM was Successfully removed (60%) using anion FIX during 1 month without regeneration. Calcium and magnesium were also successfully removed using cation FIX during the first day of operation. A significant difference in UF fouling was found after treatment of untreated surface water with cation FIX. Reversible fouling increased after cation FIX treatment, it was hypothesized that this was due to more open NOM fouling layers on the UF membrane. Irreversible fouling decreased after cation FIX treatment, it was hypothesized that this was due to less calcium-NOM complex formation.
引用
收藏
页码:334 / 341
页数:8
相关论文
共 11 条
[1]   Removal of natural organic matter by ion exchange [J].
Bolto, B ;
Dixon, D ;
Eldridge, R ;
King, S ;
Linge, K .
WATER RESEARCH, 2002, 36 (20) :5057-5065
[2]   Membrane filtration of natural organic matter: factors and mechanisms affecting rejection and flux decline with charged ultrafiltration (UF) membrane [J].
Cho, J ;
Amy, G ;
Pellegrino, J .
JOURNAL OF MEMBRANE SCIENCE, 2000, 164 (1-2) :89-110
[3]   Influence of calcium-NOM complexes on fouling of nanofiltration membranes in drinking water production [J].
Cornelissen, E. R. ;
Siegers, W. G. ;
Ogier, J. ;
Beerendonk, E. F. .
5TH WORLD WATER CONGRESS: DRINKING WATER QUALITY AND TREATMENT, 2006, 6 (04) :171-178
[4]   Removal of cyanotoxins by ultrafiltration and nanofiltration [J].
Gijsbertsen-Abrahamse, AJ ;
Schmidt, W ;
Chorus, I ;
Heijman, SGJ .
JOURNAL OF MEMBRANE SCIENCE, 2006, 276 (1-2) :252-259
[5]   Nanofiltration of a German groundwater of high hardness and NOM content:: performance and costs [J].
Gorenflo, A ;
Velázquez-Padrón, D ;
Frimmel, FH .
DESALINATION, 2003, 151 (03) :253-265
[6]   FOULING OF ULTRAFILTRATION MEMBRANES - LATERAL MIGRATION AND THE PARTICLE TRAJECTORY MODEL [J].
GREEN, G ;
BELFORT, G .
DESALINATION, 1980, 35 (1-3) :129-147
[7]   Performance of selected anion exchange resins for the treatment of a high DOC content surface water [J].
Humbert, H ;
Gallard, H ;
Suty, H ;
Croué, JP .
WATER RESEARCH, 2005, 39 (09) :1699-1708
[8]   A study of ultrafiltration membrane fouling by humic acids and flux recovery by backwashing: Experiments and modeling [J].
Katsoufidou, K ;
Yiantsios, SG ;
Karabelas, AJ .
JOURNAL OF MEMBRANE SCIENCE, 2005, 266 (1-2) :40-50
[9]   Organic fouling and chemical cleaning of nanofiltration membranes: Measurements and mechanisms [J].
Li, QL ;
Elimelech, M .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (17) :4683-4693
[10]   Desalination of surface water to industrial water with lower impact on the environment .2. Improved feed water pretreatment [J].
Mavrov, V ;
Chmiel, H ;
Heitele, B ;
Rogener, F .
DESALINATION, 1997, 110 (1-2) :65-73