Peculiarities of the small -angle scattering of laser radiation by critical CO 2

被引:4
作者
Chaikina, Ju A. [1 ]
Umanskii, S. Ya [1 ]
机构
[1] Russian Acad Sci, NN Semenov Fed Res Ctr Chem Phys, Moscow, Russia
关键词
CRITICAL-POINT; CARBON-DIOXIDE; DENSITY; OPALESCENCE; SPECTRUM; BANDS;
D O I
10.1016/j.chemphys.2020.110795
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper we propose a new theoretical model for critical opalescence describing the observed peculiarities of small angle scattering of laser radiation by critical CO2 well enough. Comparing the theoretical and experimental angular distributions of scattered light intensity we get reliable information about correlation length ~10−5 m and relative density variance ~2·10−4 for CO2 large-scale critical fluctuations. © 2020 Elsevier B.V.
引用
收藏
页数:6
相关论文
共 34 条
[1]  
Abramowitz M., 1964, National Bureau of Standards Appl. Math. Ser., V55, P364
[2]  
[Anonymous], 1978, Wave Propagation and Scattering in Random Media
[3]  
[Anonymous], 1981, Stochastic Processes in Physics and Chemistry
[4]  
[Anonymous], 1988, SOV PHYS USP, DOI DOI 10.1070/PU1988V031N04ABEH005749
[5]  
[Anonymous], 1984, Electrodynamics of Continuous Media
[6]   Broadening peculiarities of vibrational bands in the spectrum of carbon dioxide close to the critical temperature [J].
Arakcheev, V. G. ;
Bagratashvili, V. N. ;
Valeev, A. A. ;
Morozov, V. B. ;
Popov, V. K. .
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 4 (08) :1245-1251
[7]  
Behnejad Hassan., 2010, THERMODYNAMIC BEHAV
[8]   THEORY OF MULTIPLE-SCATTERING .2. CRITICAL SCATTERING [J].
BOOTS, HMJ ;
BEDEAUX, D ;
MAZUR, P .
PHYSICA A, 1976, 84 (02) :217-255
[9]   Molecular Model for Critical Opalescence of Carbon Dioxide [J].
Chaikina, Yu. A. .
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 12 (07) :1182-1192
[10]   Broadening of vibration Q-bands in the Raman spectrum of carbon dioxide due to critical density fluctuations [J].
Chaikina, Yu. A. .
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2016, 10 (07) :1039-1047