Development of a quasi-chemical viscosity model for fully liquid slags in the Al2O3-CaO-'FeO'-MgO-SiO2 system.: Part 1.: Description of the model and its application to the MgO, MgO-SiO2, Al2O3-MgO and CaO-MgO sub-systems

被引:41
作者
Kondratiev, A [1 ]
Hayes, PC [1 ]
Jak, E [1 ]
机构
[1] Univ Queensland, Sch Engn, Ctr Coal Sustainable Dev, Pyrometallurgy Res Ctr, Brisbane, Qld, Australia
关键词
slag viscosity; viscosity model; Al2O3-CaO-MgO-SiO2;
D O I
10.2355/isijinternational.46.359
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
A structurally-based quasi-chemical viscosity model for fully liquid slags in the Al2O3 CaO-'FeO'-MgO-SiO2 system has been developed. The model links the slag viscosities to the internal structures of the melts through the concentrations of various Si0.5O, Me2/nn+O and Me1/nn+Si0.25O viscous flow structural units. The concentrations of these structural units are derived from a quasi-chemical thermodynamic model of the system. The model described in this series of papers enables the viscosities of liquid slags to be predicted within experimental uncertainties over the whole range of temperatures and compositions in the Al2O3 CaOMgO-SiO2 system.
引用
收藏
页码:359 / 367
页数:9
相关论文
共 32 条
[1]   FactSage thermochemical software and databases [J].
Bale, C ;
Chartrand, P ;
Degterov, SA ;
Eriksson, G ;
Hack, K ;
Ben Mahfoud, R ;
Melançon, J ;
Pelton, AD ;
Petersen, S .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2002, 26 (02) :189-228
[2]  
Blander M., 1984, 2ND INT S MET SLAGS, P295
[3]   VISCOUS FLOW IN SILICA AND BINARY LIQUID SILICATES [J].
BOCKRIS, JO ;
MACKENZIE, JD ;
KITCHENER, JA .
TRANSACTIONS OF THE FARADAY SOCIETY, 1955, 51 (12) :1734-1748
[4]   An empirical method for the prediction of coal ash slag viscosity [J].
Browning, GJ ;
Bryant, GW ;
Hurst, HJ ;
Lucas, JA ;
Wall, TF .
ENERGY & FUELS, 2003, 17 (03) :731-737
[5]   MTDATA - Thermodynamic and phase equilibrium software from the National Physical Laboratory [J].
Davies, RH ;
Dinsdale, AT ;
Gisby, JA ;
Robinson, JAJ ;
Martin, SM .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2002, 26 (02) :229-271
[6]  
DECTEROV SA, 2004, 7 INT C MOLT SLAGS F, P839
[7]  
FINCHAM JB, 1954, P R SOC LOND, V23, P40
[8]  
Frank D.P.K.a.M., 1988, MINERAL MATTER ASH D, P89
[9]  
FRENKEL J, 1946, KINETIC THEORY LIQUI, P1
[10]  
Gaye H., 1984, METALL SOC AIME, P357