Crystal structure of bis[dihydrobis(3,5-dimethy-1-pyrazolyl)borato]cadmium(II)

被引：1

作者：

Reger, DL ^{[1
]}

Wright, TD

Rheingold, AL

Rhagitan, B

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2001年 / 31卷 / 02期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

crystal structure; poly(pyrazolyl)borate ligands; cadmium(II);

D O I：

10.1023/A:1013747123528

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of [H2B(3,5-Me(2)pz)(2)](2)Cd shows the four nitrogen donor atoms form a pseudotetrahedral arrangement about the cadmium(II). The intraligand N-Cd-N angles are restricted to an average of 91.4degrees by the chelate rings forcing the interligand N-Cd-N bond angles to average 119.4degrees. The Cd-N bond distances average 2.21 A with a range of 0.04 Angstrom. The crystal is in the triclinic space group, P (1) over bar with a = 7.6793(2) Angstrom, b = 8.5992(2) Angstrom, c = 25.0874(4) Angstrom, alpha = 91.0791(2)degrees, beta = 97.9769(4)degrees, gamma = 110.2344(6)degrees, and Z = 2.

引用

页码：93 / 95

页数：3

共 19 条

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