New Titanium Catalysts Containing Tetrazole for Cycloaddition of CO2 to Epoxides

被引：32
|
作者：
Go, Mm Jeong [1 ]
Lee, Kang Mun [2 ]
Oh, Chang Hwa [1 ]
Kang, Yi Young [1 ]
Kim, So Han [3 ]
Park, Hyoung Ryun [1 ]
Kim, Youngjo [3 ]
Lee, Junseong [1 ]
机构：
[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 361763, South Korea
[3] Chungbuk Natl Univ, Dept Chem, Chongju 361763, Chungbuk, South Korea
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 15期
基金：
新加坡国家研究基金会;
关键词：
D O I：
10.1021/om400605k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of new half-sandwich titanocene [(eta(5)-C5H5)TiLCl2] (1) and nonorganometallic titanium complexes [TiLCl3(THF)] (2) and [TiL2Cl2] (3) containing 5-(2-hydroxyphenyl)tetrazole (LH) were synthesized in high yield and fully characterized by various spectroscopic methods and X-ray crystallography. In all complexes, the ligand L acted as a monoanionic bidentate ligand and hydrogen bonding between the oxygen of the tetrahydrofuran and hydrogen of the tetrazolyl unit was observed. In the cydoaddition of CO2 to propylene oxide, complex 3 showed the highest activity among the reported Ti complexes.
引用
收藏
页码：4452 / 4455
页数：4
相关论文
共 50 条
  • [1] Iron Catalysts Containing Pyridoxal Ligands for Cycloaddition of CO2 to Epoxides
    Kang, Yi Young
    Kim, Youngjo
    Lee, Junseong
    Park, Hyoung-Ryun
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2015, 36 (04) : 1296 - 1299
  • [2] Dinuclear Aluminum Complexes as Catalysts for Cycloaddition of CO2 to Epoxides
    Kim, So Han
    Ahn, Duseong
    Go, Min Jeong
    Park, Myung Hwan
    Kim, Min
    Lee, Junseong
    Kim, Youngjo
    ORGANOMETALLICS, 2014, 33 (11) : 2770 - 2775
  • [3] Cycloaddition of CO2 to epoxides over solid base catalysts
    Tu, M
    Davis, RJ
    JOURNAL OF CATALYSIS, 2001, 199 (01) : 85 - 91
  • [4] Heteroatom-Containing Zeolites as Solid Lewis Acid Catalysts for the Cycloaddition of CO2 to Epoxides
    Gao, Bohai
    Li, Weijie
    Chai, Yuchao
    Wu, Guangjun
    Li, Landong
    CHEMCATCHEM, 2025, 17 (01)
  • [5] A series of bifunctional metalloporphyrins as efficient catalysts for cycloaddition of CO2 with epoxides
    Wang, Dan
    Gao, Ziyuan
    Duan, Sujiao
    Wei, Jiaojiao
    Ma, Linjing
    Wang, Ning
    Li, Jun
    APPLIED ORGANOMETALLIC CHEMISTRY, 2023, 37 (07)
  • [6] Mesoporous Titanium-Silicalite Zeolite Containing Organic Templates as a Bifunctional Catalyst for Cycloaddition of CO2 and Epoxides
    Liu, Dan
    Li, Gang
    Liu, Jiaxu
    Wei, Yue
    Guo, Hongchen
    ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (26) : 22119 - 22129
  • [7] Porphyrin-based homogeneous catalysts for the CO2 cycloaddition to epoxides and aziridines
    Intrieri, Daniela
    Damiano, Caterina
    Sonzini, Paolo
    Gallo, Emma
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2019, 23 (4-5) : 305 - 328
  • [8] Functionalized Ionic (Poly)Styrenes and their Application as Catalysts in the Cycloaddition of CO2 to Epoxides
    Bobbink, Felix D.
    Fei, Zhaofu
    Scopelliti, Rosario
    Das, Shoubhik
    Dyson, Paul J.
    HELVETICA CHIMICA ACTA, 2016, 99 (11) : 821 - 829
  • [9] Iron(III) Versatile Catalysts for Cycloaddition of CO2 to Epoxides and Epoxidation of Alkenes
    Cuesta-Aluja, Laia
    Masdeu-Bulto, Anna M.
    CHEMISTRYSELECT, 2016, 1 (09): : 2065 - 2070
  • [10] The CO2 cycloaddition to epoxides and aziridines promoted by porphyrin-based catalysts
    Damiano, Caterina
    Sonzini, Paolo
    Cavalleri, Matteo
    Manca, Gabriele
    Gallo, Emma
    INORGANICA CHIMICA ACTA, 2022, 540
12345