Viologen-Mediated Assembly of and Sensing with Carboxylatopillar[5]arene-Modified Gold Nanoparticles

被引:423
|
作者
Li, Hui [1 ]
Chen, Dai-Xiong [1 ]
Sun, Yu-Long [1 ]
Zheng, Yue Bing [2 ,3 ,4 ]
Tan, Li-Li [1 ]
Weiss, Paul S. [2 ,3 ,4 ]
Yang, Ying-Wei [1 ]
机构
[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
[2] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA
[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[4] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
基金
美国国家科学基金会; 高等学校博士学科点专项科研基金; 中国国家自然科学基金;
关键词
FACILE SYNTHESIS; GROWTH-MECHANISM; SURFACE; HOST; CITRATE; ACID; NANOCRYSTALS; REDUCTION; PROGRESS; SHAPE;
D O I
10.1021/ja3115168
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carboxylatopillar[5]arene (CP[5]A), a new water-soluble macrocyclic synthetic receptor, has been employed as a stabilizing ligand for in situ preparation of gold nanoparticles (AuNPs) to gain new insights into supramolecular host-AuNP interactions. CP[5]A-modified AuNPs with good dispersion and narrow size distributions (3.1 +/- 0.5 nm) were successfully produced in aqueous solution, suggesting a green synthetic pathway for the application of AuNPs in biological systems. Supramolecular self-assembly of CP[5]A-modified AuNPs mediated by suitable guest molecules was also investigated, indicating that the new hybrid material is useful for sensing and detection of the herbicide paraquat.
引用
收藏
页码:1570 / 1576
页数:7
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