Physical Properties of HCFO-1233zd(E)

被引:89
作者
Hulse, Ryan J. [1 ]
Basu, Rajat S. [1 ]
Singh, Rajiv R. [1 ]
Thomas, Raymond H. P. [1 ]
机构
[1] Honeywell Int Inc, Buffalo, NY 14210 USA
关键词
D O I
10.1021/je300776s
中图分类号
O414.1 [热力学];
学科分类号
摘要
A new low global warming potential (GWP) fluid hydrochlorofluoroolefin trans-isomer of 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)) has been developed in our laboratory. HCFO-1233zd(E) has a very short atmospheric lifetime of 26 days and a global warming potential (GWP) of less than 5 (Wong et al., http://www.honeywell-solsticelba.com. product-info/environmental-regulatory/#atmospheric-impact, 2012). This makes it an excellent environmentally friendly candidate for many applications including refrigeration, foam expansion agents, and as solvents. In this work we have presented our measurements of physical properties like the boiling point, critical temperature, vapor pressure, liquid density, and surface tension of HCFO-1233zd(E). We have also provided our calculated ideal gas heat capacity at constant pressure using quantum mechanical theory. Temperature-dependent properties are correlated with standard forms of equations and described in the paper.
引用
收藏
页码:3581 / 3586
页数:6
相关论文
共 15 条
  • [1] Basu R. S., 2012, PAPER PRESENTED AT T
  • [2] THERMO-PHYSICAL PROPERTIES OF 1,1,1,2-TETRAFLUOROETHANE (R-134A)
    BASU, RS
    WILSON, DP
    [J]. INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1989, 10 (03) : 591 - 603
  • [3] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE
    BECKE, AD
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) : 5648 - 5652
  • [4] Geller V., COMMUNICATION
  • [5] Hulse R. J., 2009, PROCEEDINGS OF THE 1
  • [6] Uncertainties in scaling factors for ab initio vibrational frequencies
    Irikura, KK
    Johnson, RD
    Kacker, RN
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (37) : 8430 - 8437
  • [7] Surface tension measurements of 1,1,1,3,3-pentafluoropropane (HFC-245fa) and 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) from 254 to 333 K
    Lin, H
    Duan, YY
    Wang, ZW
    [J]. FLUID PHASE EQUILIBRIA, 2003, 214 (01) : 79 - 86
  • [8] STRATOSPHERIC SINK FOR CHLOROFLUOROMETHANES - CHLORINE ATOMIC-CATALYSED DESTRUCTION OF OZONE
    MOLINA, MJ
    ROWLAND, FS
    [J]. NATURE, 1974, 249 (5460) : 810 - 812
  • [9] OH REACTION-KINETICS AND ATMOSPHERIC LIFETIME ESTIMATES FOR SEVERAL HYDROFLUOROCARBONS
    NELSON, DD
    ZAHNISER, MS
    KOLB, CE
    MAGID, H
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (44) : 16301 - 16306
  • [10] CF3CF=CH2 and (Z)-CF3CF=CHF:: temperature dependent OH rate coefficients and global warming potentials
    Papadimitriou, Vassileios C.
    Talukdar, Ranajit K.
    Portmann, R. W.
    Ravishankara, A. R.
    Burkholder, James B.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (06) : 808 - 820