Poly(para-arylene)s via [2+2+2]

被引：7

作者：

Batson, Joel M. ^{[1
]}

Swager, Timothy M. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ACS MACRO LETTERS | 2012年 / 1卷 / 09期

基金：

美国国家科学基金会;

关键词：

SOLUBLE POLY(PARA-PHENYLENE)S; POLYPHENYLENE; POLY(P-PHENYLENE); POLYMERIZATION; CATALYST; ACID;

D O I：

10.1021/mz300352m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations.

引用

收藏

页码：1121 / 1123

页数：3

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