Jahn-Teller Distortion of Hydrocarbon Cations Probed by Infrared Photodissociation Spectroscopy

被引：8

作者：

Crestoni, Maria Elisa ^{[1
]}

Fornarini, Simonetta ^{[1
]}

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim & Tecnol Farmaco, I-00185 Rome, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 30期

关键词：

IR spectroscopy; Jahn-Teller effect; radical cations; structure elucidation; vibronic interactions; PHOTON DISSOCIATION SPECTROSCOPY; GAS-PHASE; IONS; ADAMANTANE; COMPLEXES;

D O I：

10.1002/anie.201201650

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Frozen distortion or fluxional system? The IR spectrum of ionized adamantane probes the distorted geometry predicted by the Jahn-Teller theorem, testifying the potential of infrared photon dissociation action spectroscopy in revealing fundamental vibrational and electronic features of isolated charged molecules (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7373 / 7375

页数：3

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