Synthesis and electrochemical characterization of donor-acceptor phenylazomethine dendrimers

被引：13
|
作者：
Juárez, R [1 ]
Gómez, R [1 ]
Segura, JL [1 ]
Seoane, C [1 ]
机构：
[1] Univ Complutense, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 51期
关键词：
D O I：
10.1016/j.tetlet.2005.10.073
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of the first donor acceptor phenylazomethine dendrimers (4 and 5) is described. A convergent method is used via the condensation of aromatic ketones with an appropriately functionalized tri(aminophenyl)-s-triazine promoted by titanium (IV) chloride. Cyclic voltammetry investigations show a donor-acceptor behaviour due to the presence of the electron acceptor s-triazine core and the donor ability of the conjugated peripheral butoxybenzene units. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8861 / 8864
页数：4
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