Activation of the fly ash pozzolanic reaction by hydrothermal conditions

被引:82
作者
Goñi, S [1 ]
Guerrero, A [1 ]
Luxán, MP [1 ]
Macías, A [1 ]
机构
[1] CSIC, Inst Construct Sci Eduardo Torroja, Madrid 28033, Spain
关键词
hydrothermal; hydration products; fly ash; cement manufacture;
D O I
10.1016/S0008-8846(03)00085-1
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The effect of hydrothermal treatment on the pozzolanic reaction of two kinds of Spanish fly ashes from coal combustion (ASTM class F) is discussed. Characterization of the compounds formed as a result of hydrothermal treatment and the changes provoked in the starting fly ashes were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and infrared (IR) spectroscopy. alpha-C2SH, CSH gel, different solid solutions of katoites (the cubic crystallographic variety of hydrogamets series (C(3)ASH(4))) and a mixed oxide (CaFe2O4) were formed depending on the kind of fly ash. The hydrated compounds are precursors of a new kind of low-energy cement called fly ash belite cement (FABC); besides, they have potential properties to intercalate toxic ions and therefore can be used as immobilization systems of these ions. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1399 / 1405
页数:7
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