Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4′-diazenediyldiphthalic acid ligand

被引：10
作者：
Lu, Lu [1 ,2 ]
Wang, Jun [1 ,2 ]
Bai, Jian-Wei [1 ]
Hou, Yang [1 ]
Yang, Bin [1 ]
Zhao, Bao-Zhong [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China
[2] Sichuan Univ Sci & Engn, Dept Chem, Zigong 643000, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2008年 / 43卷 / 12期
关键词：
Cd complex; crystal structure; topology;
D O I：
10.1002/crat.200800086
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
An exploration of the cadmium-L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L)(0.5)(H2O)(3)]}(n) (1) (H4L = 4,4'-diazenediyldiphthalic acid). Single-crystal X-ray analysis reveals that it crystallizes in the triclinic space group P-1. a = 5.746(3) angstrom, b = 6.526(4) angstrom, c = 14.701(8) angstrom, alpha = 92.348(8)degrees, beta = 99.622(6)degrees, gamma = 106.877(7)degrees. The Cd-II ions are linked into an extended 2-D rectangle-like structure via L ligands, which exhibits an attractive three-connected honeycomb topological network. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：1327 / 1330
页数：4
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