Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4′-diazenediyldiphthalic acid ligand

被引：10

作者：

Lu, Lu ^{[1
,2
]}

Wang, Jun ^{[1
,2
]}

Bai, Jian-Wei ^{[1
]}

Hou, Yang ^{[1
]}

Yang, Bin ^{[1
]}

Zhao, Bao-Zhong ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China

[2] Sichuan Univ Sci & Engn, Dept Chem, Zigong 643000, Peoples R China

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 2008年 / 43卷 / 12期

关键词：

Cd complex; crystal structure; topology;

D O I：

10.1002/crat.200800086

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

An exploration of the cadmium-L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L)(0.5)(H2O)(3)]}(n) (1) (H4L = 4,4'-diazenediyldiphthalic acid). Single-crystal X-ray analysis reveals that it crystallizes in the triclinic space group P-1. a = 5.746(3) angstrom, b = 6.526(4) angstrom, c = 14.701(8) angstrom, alpha = 92.348(8)degrees, beta = 99.622(6)degrees, gamma = 106.877(7)degrees. The Cd-II ions are linked into an extended 2-D rectangle-like structure via L ligands, which exhibits an attractive three-connected honeycomb topological network. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1327 / 1330

页数：4

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