Immobilizing Cr3+ with SO3H-functionalized solid polymeric ionic liquids as efficient and reusable catalysts for selective transformation of carbohydrates into 5-hydroxymethylfurfural

被引：80

作者：

Li, Hu ^{[1
]}

Zhang, Qiuyun ^{[1
]}

Liu, Xiaofang ^{[1
]}

Chang, Fei ^{[1
]}

Zhang, Yuping ^{[1
]}

Xue, Wei ^{[1
]}

Yang, Song ^{[1
]}

机构：

[1] Guizhou Univ, Minist Educ, Key Lab Green Pesticide & Agr Bioengn,State Key L, Ctr Res & Dev Fine Chem,State Local Joint Engn La, Guiyang 550025, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2013年 / 144卷

关键词：

Renewable resources; Valuable chemicals; Biofuels; Reusable catalyst; Polymeric ionic liquids; HETEROGENEOUS CATALYSTS; ACID CATALYST; FRUCTOSE; DEHYDRATION; CONVERSION; GLUCOSE; SACCHARIDES; HYDROLYSIS; CELLULOSE; KINETICS;

D O I：

10.1016/j.biortech.2013.06.063

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

A series of functional polymeric ionic liquids (FPILs) were prepared by coupling of SO3H-functionalized polymeric ionic liquids with different counterpart anions containing or excluding CrCl3 center dot 6H(2)O, and characterized by SEM, FT-IR, XRD, NH3-TPD, TG, melting point, ICP-AES, and TEM. The catalytic activity of the prepared solid FPILs was investigated for the conversion of biomass including fructose, glucose and cellulose into 5-hydroxymethylfurfural (HMF) with the presence of DMSO-mediated solvents, successively producing moderate to excellent yields of HMF under atmospheric pressure. The FPILs catalysts developed in this study present improved performance on fructose-to-HMF conversion over other solid catalysts, such as functional ionic liquids supported by silica, metal oxides and strong acid ion exchange resin catalysts, and can be very easily recycled at least five times without significant loss of activity. In addition, a kinetic analysis was carried out to illustrate the formation of HMF. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：21 / 27

页数：7

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