Crystalline Properties and Strain Relaxation Mechanism of CVD Grown GeSn

被引:119
作者
Gencarelli, F. [1 ,2 ]
Vincent, B. [1 ]
Demeulemeester, J. [3 ]
Vantomme, A. [3 ]
Moussa, A. [1 ]
Franquet, A. [1 ]
Kumar, A. [1 ,3 ]
Bender, H. [1 ]
Meersschaut, J. [1 ]
Vandervorst, W. [1 ,3 ]
Loo, R. [1 ]
Caymax, M. [1 ]
Temst, K. [3 ]
Heyns, M. [1 ,2 ]
机构
[1] IMEC, B-3001 Louvain, Belgium
[2] Katholieke Univ Leuven, MTM Dept, B-3001 Louvain, Belgium
[3] Katholieke Univ Leuven, IKS, B-3001 Louvain, Belgium
基金
日本学术振兴会;
关键词
CHEMICAL-VAPOR-DEPOSITION; EPITAXIAL-GROWTH; VEGARDS LAW; INXGA1-XAS; THICKNESS; ISLANDS; LAYER;
D O I
10.1149/2.011304jss
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this contribution, we discuss the crystalline properties of strained and strain-relaxed CVD-grown GeSn layers with Sn content in the range 6.4-12.6 at.%. A positive deviation from Vegard's law was observed and a new experimental bowing parameter was extracted for GeSn: b(GeSn) = 0.041 angstrom (in excellent agreement with recent theoretical predictions). The GeSn critical thickness for strain relaxation as a function of Sn concentration was determined, resulting in significantly higher values than those predicted by equilibrium models. A composition-dependent strain relaxation mechanism was also found, with the formation of an increasing density of GeSn pyramidal islands in addition to misfit dislocations at lower Sn concentration. (C) 2013 The Electrochemical Society. All rights reserved.
引用
收藏
页码:P134 / P137
页数:4
相关论文
共 27 条
[11]   ACTIVATION BARRIERS TO STRAIN RELAXATION IN LATTICE-MISMATCHED EPITAXY [J].
HULL, R ;
BEAN, JC ;
WERDER, DJ ;
LEIBENGUTH, RE .
PHYSICAL REVIEW B, 1989, 40 (03) :1681-1684
[12]   ELECTRONIC-PROPERTIES OF METASTABLE GEXSN1-X ALLOYS [J].
JENKINS, DW ;
DOW, JD .
PHYSICAL REVIEW B, 1987, 36 (15) :7994-8000
[13]   Influence of HCl on the chemical vapor deposition and etching of Ge islands on Si(001) [J].
Kamins, TI ;
Briggs, GAD ;
Williams, RS .
APPLIED PHYSICS LETTERS, 1998, 73 (13) :1862-1864
[14]   Test of Vegard's law in thin epitaxial SiGe layers [J].
Kasper, E ;
Schuh, A ;
Bauer, G ;
Hollander, B ;
Kibbel, H .
JOURNAL OF CRYSTAL GROWTH, 1995, 157 (1-4) :68-72
[15]   Tin-based group IV semiconductors: New platforms for opto- and microelectronics on silicon [J].
Kouvetakis, J. ;
Menendez, J. ;
Chizmeshya, A. V. G. .
ANNUAL REVIEW OF MATERIALS RESEARCH, 2006, 36 (497-554) :497-554
[16]   High Quality Ge Virtual Substrates on Si Wafers with Standard STI Patterning [J].
Loo, R. ;
Wang, G. ;
Souriau, L. ;
Lin, J. C. ;
Takeuchi, S. ;
Brammertz, G. ;
Caymax, M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (01) :H13-H21
[17]  
MATTHEWS JW, 1974, J CRYST GROWTH, V27, P118, DOI 10.1016/S0022-0248(74)80055-2
[18]   Molecular beam deposition of Al2O3 on p-Ge(001)/Ge0.95Sn0.05 heterostructure and impact of a Ge-cap interfacial layer [J].
Merckling, C. ;
Sun, X. ;
Shimura, Y. ;
Franquet, A. ;
Vincent, B. ;
Takeuchi, S. ;
Vandervorst, W. ;
Nakatsuka, O. ;
Zaima, S. ;
Loo, R. ;
Caymax, M. .
APPLIED PHYSICS LETTERS, 2011, 98 (19)
[19]   Versatile buffer layer architectures based on Ge1-xSnx alloys -: art. no. 191912 [J].
Roucka, R ;
Tolle, J ;
Cook, C ;
Chizmeshya, AVG ;
Kouvetakis, J ;
D'Costa, V ;
Menendez, J ;
Chen, ZD ;
Zollner, S .
APPLIED PHYSICS LETTERS, 2005, 86 (19) :1-3
[20]   KINETICALLY CONTROLLED CRITICAL THICKNESS FOR COHERENT ISLANDING AND THICK HIGHLY STRAINED PSEUDOMORPHIC FILMS OF INXGA1-XAS ON GAAS(100) [J].
SNYDER, CW ;
MANSFIELD, JF ;
ORR, BG .
PHYSICAL REVIEW B, 1992, 46 (15) :9551-9554