Ecosustainable Development of Novel Bio-inorganic Hybrid Materials as UV Protection Systems for Potential Cosmetic Applications

被引:2
|
作者
Villa, Carla [1 ]
Lacapra, Chiara [1 ]
Rosa, Roberto [2 ]
Veronesi, Paolo [2 ]
Leonelli, Cristina [2 ]
机构
[1] Univ Genoa, Sect Drug & Cosmet Chem, Dept Pharm, I-16132 Genoa, Italy
[2] Univ Modena & Reggio Emilia, Dept Engn Enzo Ferrari, I-41125 Modena, Italy
关键词
Microwaves; hydrothermal process; green chemistry; cosmetic bio-inorganic hybrid material; UV protection system; organoclay; LAYERED DOUBLE HYDROXIDES; ANIONIC CLAYS; SKIN-CANCER; SUNSCREEN USE; MICROWAVE; INTERCALATION; PHOTOSTABILITY; SAFE; ACID; PHOTOPROTECTION;
D O I
10.2174/1389201016666150817094847
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A new organoclay, bio-inorganic hybrid material, was successfully prepared following the "green chemistry" principles, exploiting microwave irradiation (as an alternative energetic source) in both the solvent-free synthesis of the organic filler (UVB filter) and in its hydrothermal intercalation in a sodium Bentonite clay (renewable natural inorganic source at low temperature). The organic filler is a benzylidene camphor derivative with the same cationic moiety as the well-known UV filter camphor benzalkonium methosulfate. The aim of the research was the ecosustainable development of a new UV protection model, suitable for use in cosmetic and pharmaceutical products, with potential advantages of stability, efficiency and safety compared to the commercially available UVB sunscreens. The organically modified clay was thoroughly investigated using X-ray diffraction (XRD), infrared spectroscopy (IR), thermo gravimetric analysis and differential thermal analysis (DTA). Results confirmed the complete intercalation of the organic filler in the interlayer region of the smectite clay, leading to a new bio-inorganic hybrid material with potential for cosmetic and pharmaceutical applications in the UV protection field, as confirmed by preliminary photochemical studies. This work represents the first example in the use of Na-Bentonite cationic clay (usually employed as rheological additive) as hosting agent of the synthesized quaternary UVB filter, as well as in the complete MW-assisted preparation of the organoclay, starting from the synthesis of the organic UV sunscreen to its hydrothermal intercalation.
引用
收藏
页码:1070 / 1077
页数:8
相关论文
共 43 条
  • [31] A novel UV-cured interpenetrating organic-inorganic hybrid polymer network based phase change materials (IPN-PCM)
    Basturk, Emre
    Deniz, Duygu Yuksel
    Sen, Ferhat
    Kahraman, Memet Vezir
    POLYMER ENGINEERING AND SCIENCE, 2018, 58 (06): : 870 - 875
  • [32] Development of highly efficient two-photon absorption materials: Organic dye-inorganic nanolayered silicate hybrid systems
    Tanamura, Y
    Kamada, K
    Misawa, H
    2005 PACIFIC RIM CONFERENCE ON LASERS AND ELECTRO-OPTICS, 2005, : 859 - 860
  • [33] Recent progress on synthesis and modifications of ZnIn2S4 based novel hybrid materials for potential applications
    Yadav, Gaurav
    Ahmaruzzaman, Md.
    MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2023, 292
  • [34] Ab initio study of multifunctional novel CsErZnM3(M = Se, Te) chalcogenides: potential materials for UV protection and energy harvesting
    Khan, Muhammad Salman
    Gul, Banat
    Mohamed, Abdelhay Salah
    Aziz, Siti Maisarah
    Ahmad, Hijaz
    Abbas, Faheem
    PHYSICA SCRIPTA, 2025, 100 (01)
  • [35] Development of novel UV cross-linkable materials for enhancing planarity in via applications via the correlation of simulated and experimental analyses
    Takei, Satoshi
    Lin, Michael W.
    Yoon, Sangwoong
    Ohashi, Tomoya
    Nakajima, Yasuyuki
    Willson, C. Grant
    ADVANCES IN RESIST MATERIALS AND PROCESSING TECHNOLOGY XXVI, 2009, 7273
  • [36] Interoperability of Materials Database Systems in Support of Nuclear Energy Development and Potential Applications for Fuel Cell Material Selection
    Lin, L.
    Austin, T.
    Ren, W.
    MATERIALS PERFORMANCE AND CHARACTERIZATION, 2015, 4 (01) : 115 - 130
  • [37] Fabrication of multifunctional bio-macromolecule organic-inorganic hybrid system for protein silk: Photochromic, UV protection, fire-proof and super durability (vol 253, 127296, 2023)
    Jin, Wen-Jie
    Xin, Yu
    Guan, Jin-Ping
    Cheng, Xian-Wei
    Zhu, Meng-Kai
    Wang, Dong
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2025, 302
  • [38] Recent development towards the novel applications and future prospects for cellulose-metal organic framework hybrid materials: a review
    Qamar, Zeenat
    Aslam, Awais Ali
    Fatima, Farheen
    Hassan, Sadaf Ul
    Nazir, Muhammad Shahid
    Ali, Zulfiqar
    Awad, Sameer Ahmed
    Khan, Aqeel Ahmad
    Environmental Science and Pollution Research, 2024, 31 (55) : 63501 - 63523
  • [39] Development and Applications of a Novel QM/MM Hybrid Molecular Dynamics Calculation System on Highly Parallel Supercomputer Systems
    Tateno, Masaru
    Hagiwara, Yohsuke
    Kang, Jiyoung
    BIOPHYSICAL JOURNAL, 2010, 98 (03) : 572A - 572A
  • [40] Band-Gap Engineering of Zinc Oxide Colloids via Lattice Substitution with Sulfur Leading to Materials with Advanced Properties for Optical Applications Like Full Inorganic UV Protection
    Lehr, Daniela
    Luka, Martin
    Wagner, Markus R.
    Buelger, Max
    Hoffmann, Axel
    Polarz, Sebastian
    CHEMISTRY OF MATERIALS, 2012, 24 (10) : 1771 - 1778