Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry

被引：164

作者：

Liu, Dong ^{[1
]}

Ma, Hong-Xing ^{[2
]}

Fang, Ping ^{[1
]}

Mei, Tian-Sheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Ctr Excellence Mol Synth, 345 Lingling Lu, Shanghai 200032, Peoples R China

[2] Yancheng Inst Technol, Sch Chem & Chem Engn, Yancheng 224051, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 15期

关键词：

nickel; electrocatalysis; electrosynthesis; thiolation; thiyl radicals; CROSS-COUPLING REACTIONS; FORMING REDUCTIVE ELIMINATION; S BOND FORMATION; C-H THIOLATION; TRANSITION-METAL; ORGANIC ELECTROSYNTHESIS; PAIRED ELECTROLYSIS; DIARYL SULFIDES; THIOLS; CARBON;

D O I：

10.1002/anie.201900956

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition-metal-catalyzed coupling reactions are useful tools for synthesizing aryl sulfur compounds. However, conventional transition-metal-catalyzed thiolation of aryl bromides and chlorides typically requires the use of strong base under elevated reaction temperature. Herein, we report the first examples of nickel-catalyzed electrochemical thiolation of aryl bromides and chlorides in the absence of an external base at room temperature using undivided electrochemical cells.

引用

页码：5033 / 5037

页数：5

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