Asymmetric reduction of imines

被引：10

作者：

Hashiguchi, S

Uematsu, N

Noyori, R

机构：

[1] NAGOYA UNIV, DEPT CHEM, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN

[2] NAGOYA UNIV, MOL CHIRAL RES UNIT, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1997年 / 55卷 / 02期

关键词：

asymmetric reduction; borane reagent; chiral amines; chiral ligand; hydrogenation; hydrosilylation; imines; transfer hydrogenation; triethylammonium formate;

D O I：

10.5059/yukigoseikyokaishi.55.99

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Of all options enantioselective reduction of imines is the most straightforward method for preparation of optically active amines. This asymmetric transformation can be accomplished by stoichiometric or catalytic hydroboration, aluminium hydride reduction, and, more efficiently, transition metal catalyzed reduction with organosilanes, molecular hydrogen, and formic acid. Various chiral catalysts containing Ti, Rh, Ir, and Ru have been developed for this purpose. This review summarizes the recent progress in this subject.

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页码：99 / 109

页数：11

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