Solubilities of CO2, H2, N2 and O2 in ionic liquid 1-n-butyl-3-methylimidazolium heptafluorobutyrate

被引：48

作者：

Zhou, Lingyun ^{[1
,2
]}

Fan, Jing ^{[1
]}

Shang, Xiaomin ^{[1
]}

Wang, Jianji ^{[1
]}

机构：

[1] Henan Normal Univ, Henan Key Lab Environm Pollut Control, Sch Chem & Environm Sci, Xinxiang 453007, Henan, Peoples R China

[2] Henan Inst Sci & Technol, Coll Resource & Environm, Xinxiang 453007, Henan, Peoples R China

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2013年 / 59卷

基金：

中国国家自然科学基金;

关键词：

CO2; solubility; Ionic liquid; Henry's constant; Pitzer model; 1-n-Butyl-3-methylimidazolium heptafluorobutyrate; CARBON-DIOXIDE SOLUBILITY; PRESSURE PHASE-BEHAVIOR; GAS SOLUBILITY; TEMPERATURE; SPECTROSCOPY; SEPARATIONS; ABSORPTION; SOLVATION; KINETICS; CAPTURE;

D O I：

10.1016/j.jct.2012.11.030

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Ionic liquids (ILs) are promising in the capture and separation of CO2. In this work, IL 1-n-butyl-3-methylimidazolium heptafluorobutyrate, [C(4)mim][CF3CF2CF2COO], has been synthesized and characterized by H-1, C-13 and F-19 NMR spectra. Solubilities of CO2, H-2, N-2 and O-2 in this IL have been determined at the temperature range from (303.15 to 333.15) K and the pressure up to 8.9 MPa. From these data, the Henry's constant, the standard state solution Gibbs energy, standard state solution enthalpy and standard state solution entropy of these gases in [C(4)mim][CF3CF2CF2COO] were derived and analyzed from molecular interactions. It was shown that the solubility of CO2 is obviously higher than that in [C(4)mim] [CF3COO] and [C(4)mim][CF3SO3] reported in literature, which makes this IL an attractive solvent for gas separation processes. Furthermore, these solubility data were well correlated by Pitzer model. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：28 / 34

页数：7

共 50 条

[21] Afterglow of Argon Plasmas with H2, O2, N2, and CO2 Admixtures Observed by Thomson Scattering [J].

Hubner, Simon ;

Carbone, Emile ;

Palomares, Jose Maria ;

van der Mullen, Joost .

PLASMA PROCESSES AND POLYMERS, 2014, 11 (05) :482-488

[22] Comparison of the Reburning Chemistry in O2/N2, O2/CO2, and O2/H2O Atmospheres [J].

He, Yizhuo ;

Luo, Jianghui ;

Li, Yangguang ;

Jia, Huiqiao ;

Wang, Feng ;

Zou, Chun ;

Zheng, Chuguang .

ENERGY & FUELS, 2017, 31 (10) :11404-11412

[23] Effect of partial pressure on CO2 solubility in ionic liquid mixtures of 1-butyl-3-methylimidazolium acetate and 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide [J].

Kanakubo, Mitsuhiro ;

Makino, Takashi ;

Umecky, Tatsuya ;

Sakurai, Masato .

FLUID PHASE EQUILIBRIA, 2016, 420 :74-82

[24] Density functional theory study on the mechanism of absorption of CO2 by the ionic liquid 1-butyl-3-methylimidazolium acetate [J].

Yan-Fe, Chen ;

Yan-Hong, Cui ;

Dong-Shun, Deng ;

Ning, Ai ;

Long, Ye .

PROGRESS IN REACTION KINETICS AND MECHANISM, 2014, 39 (02) :197-208

[25] Collisional deactivation of N2(C3Πu, v=0, 1, 2, 3) states by N2, O2, H2 and H2O molecules [J].

Pancheshnyi, SV ;

Starikovskaia, SM ;

Starikovskii, AY .

CHEMICAL PHYSICS, 2000, 262 (2-3) :349-357

[26] Simulated Raman libraries of gaseous CO, H2, N2, O2, CO2, and H2O for high-temperature diagnostics [J].

Lill, Johannes ;

Dreizler, Andreas ;

Geyer, Dirk .

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2025, 340

[27] An experimental study and numerical modeling of combusting two coal chars in a drop-tube reactor: A comparison between N2/O2, CO2/O2, and N2/CO2/O2 atmospheres [J].

Tolvanen, Henrik ;

Raiko, Risto .

FUEL, 2014, 124 :190-201

[28] High pressure solubility of CH4, N2O and N2 in 1-butyl-3-methylimidazolium dicyanamide: Solubilities, selectivities and soft-SAFT modeling [J].

Pereira, Luis M. C. ;

Martins, Vania ;

Kurnia, Kiki Adi ;

Oliveira, Mariana B. ;

Dias, Ana M. A. ;

Llovell, Felix ;

Vega, Lourdes F. ;

Carvalho, Pedro J. ;

Coutinho, Joao A. P. .

JOURNAL OF SUPERCRITICAL FLUIDS, 2016, 110 :56-64

[29] Investigations on Pressure Broadening Coefficients of NO Lines in the 1←0 Band for N2, CO2, Ar, H2, O2 and He [J].

Agarwal, Sumit ;

Seifert, Leopold ;

Zhu, Denghao ;

Shu, Bo ;

Fernandes, Ravi ;

Qu, Zhechao .

APPLIED SCIENCES-BASEL, 2023, 13 (03)

[30] Density functional theory study on the absorption of CO2 by the ionic liquid of 1-butyl-3-methylimidazolium acetate [J].

Chen Yan-Fei ;

Cui Yan-Hong ;

Deng Dong-Shun ;

Ai Ning .

ENVIRONMENTAL PROTECTION AND RESOURCES EXPLOITATION, PTS 1-3, 2013, 807-809 :543-548

← 1 2 3 4 5 →