Role of polymer in the catalysis of acyl transfer reactions

被引：0
|
作者：
Alwar, S. Bangaru Sudarsan [1 ]
Kumar, P. Vijaya [1 ]
Kamali, T. V. [1 ]
机构：
[1] Dwaraka Doss Goverdhan Doss Vaishnav Coll, Dept Chem, Madras 600106, Tamil Nadu, India
来源：
ASIAN JOURNAL OF CHEMISTRY | 2008年 / 20卷 / 01期
关键词：
polymer; catalysis; acyl transfer;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Preliminary study of kinetics of the hydrolysis of esters in the presence of polymer polyethyleneglycol (PEG) 6000 by hydroxide ion in varying solvent media has been carried out conductometrically. The results obtained throw light on the role of the catalysts in the mechanism of hydrolysis of esters. Further, the presence of polymer is found to modify the role of solvent during the course of the reaction. These preliminary results will pave way for predicting the nature of attack by enzymes on various substrates in biochemical reactions.
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页码：505 / 508
页数：4
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