The Origin of the Activity of Amine-Functionalized Metal-Organic Frameworks in the Catalytic Synthesis of Cyclic Carbonates from Epoxide and CO2

被引：95
作者：
Lescouet, Tristan [1 ]
Chizallet, Celine [2 ]
Farrusseng, David [1 ]
机构：
[1] Univ Lyon, Inst Rech Catalyse & Environm Lyon IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France
[2] IFP Energies Nouvelles, F-69360 Solaize, France
来源：
CHEMCATCHEM | 2012年 / 4卷 / 11期
关键词：
ab initio calculations; amines; Bronsted sites; carbonates; metal-organic frameworks; AMORPHOUS SILICA-ALUMINA; DIOXIDE; MOFS; PHOTOCATALYSTS; ACTIVATION; ADSORPTION; ALGORITHM; ACIDITY; SITES; FTIR;
D O I：
10.1002/cctc.201200288
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
[No abstract available]
引用
收藏
页码：1725 / 1728
页数：4
相关论文
共 37 条
[1]   Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology [J].
Ahnfeldt, Tim ;
Gunzelmann, Daniel ;
Loiseau, Thierry ;
Hirsemann, Dunja ;
Senker, Juergen ;
Ferey, Gerard ;
Stock, Norbert .
INORGANIC CHEMISTRY, 2009, 48 (07) :3057-3064
[2]  
[Anonymous], 2009, ANGEW CHEM INT ED, V48, P7502
[3]   Amine functionalised metal organic frameworks (MOFs) as adsorbents for carbon dioxide [J].
Arstad, Bjornar ;
Fjellvag, Helmer ;
Kongshaug, Kjell Ove ;
Swang, Ole ;
Blom, Richard .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2008, 14 (06) :755-762
[4]   Adsorption and vibrational spectroscopy of ammonia at mordenite:: Ab initio study [J].
Bucko, T ;
Hafner, J ;
Benco, L .
JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (21) :10263-10277
[5]   Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts [J].
Caló, V ;
Nacci, A ;
Monopoli, A ;
Fanizzi, A .
ORGANIC LETTERS, 2002, 4 (15) :2561-2563
[6]   Acidity of Amorphous Silica-Alumina: From Coordination Promotion of Lewis Sites to Proton Transfer [J].
Chizallet, Celine ;
Raybaud, Pascal .
CHEMPHYSCHEM, 2010, 11 (01) :105-108
[7]  
Farrusseng D., 2009, Angew. Chem., V121, P7638
[8]   Amino-based metal-organic frameworks as stable, highly active basic catalysts [J].
Gascon, Jorge ;
Aktay, Ugur ;
Hernandez-Alonso, Maria D. ;
van Klink, Gerard P. M. ;
Kapteijn, Freek .
JOURNAL OF CATALYSIS, 2009, 261 (01) :75-87
[9]   Isoreticular MOFs as Efficient Photocatalysts with Tunable Band Gap: An Operando FTIR Study of the Photoinduced Oxidation of Propylene [J].
Gascon, Jorge ;
Hernandez-Alonso, Maria D. ;
Almeida, Ana Rita ;
van Klink, Gerard P. M. ;
Kapteijn, Freek ;
Mul, Guido .
CHEMSUSCHEM, 2008, 1 (12) :981-983
[10]   Semiempirical GGA-type density functional constructed with a long-range dispersion correction [J].
Grimme, Stefan .
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2006, 27 (15) :1787-1799
1234