Components Interaction of Cotton Stalk under Low-Temperature Hydrothermal Conversion: A Bio-Oil Pyrolysis Behavior Perspective Analysis

被引：6
作者：
Yang, Xiao [1 ]
Chen, Naihao [1 ]
Ge, Shengbo [2 ]
Sheng, Yequan [2 ]
Yang, Kun [1 ]
Lin, Pengmusen [1 ]
Guo, Xuqiang [1 ]
Lam, Su Shiung [2 ,3 ]
Ming, Hui [1 ]
Zhang, Libo [1 ]
机构：
[1] China Univ Petr Beijing Karamay, Coll Engn, State Key Lab Heavy Oil Proc, Karamay 834000, Peoples R China
[2] Nanjing Forestry Univ, Coll Mat Sci & Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China
[3] Univ Malaysia Terengganu, Higher Inst Ctr Excellence HICoE, Inst Trop Aquaculture & Fisheries AKUATROP, Kuala Nerus 21030, Malaysia
来源：
POLYMERS | 2022年 / 14卷 / 20期
基金：
美国国家科学基金会;
关键词：
bio-oil; cotton stalk; hydro-thermal liquefaction; interaction; multi-variate blending; CELLULOSE-LIGNIN INTERACTIONS; LIGNOCELLULOSIC BIOMASS; LIQUEFACTION; HEMICELLULOSE; GASIFICATION; CONSTITUENTS; PROTEIN; XYLAN;
D O I：
10.3390/polym14204307
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The conversion of agricultural and forestry waste biomass materials into bio-oil by mild hydro-thermal technology has a positive effect on extending the agricultural industry chain and alleviating the world energy crisis. The interaction investigation of biomass components during bio-oil formation can be significant for the efficient conversion of lignocellulose when different raw materials are fed together. In this paper, a bio-oil pyrolysis behavior (thermogravimetric analysis, TG) perspective component interaction investigation of cotton stalks under low-temperature hydro-thermal conversion (220 degrees C) was studied. Cellulose, hemi-cellulose, lignin, and protein were used as lignocellulose model components, by their simple binary blending and multi-variate blending and combined with thermo-gravimetric analysis and gas chromatography-mass spectrometry (GC-MS) characterization and analysis. The interaction of different model components and real biomass raw material components in the hydro-thermal process was explored. Results showed that the components of hydro-thermal bio-oil from cotton stalks were highly correlated with the interactions between cellulose, hemi-cellulose, lignin, and protein. During the hydro-thermal process, cellulose and hemi-cellulose inhibit each other, which reduces the content of ketones, aldehydes, ethers, and alcohols in bio-oil. Interaction between cellulose and lignin was obvious, which promotes the formation of oligomers, such as ketones, aldehydes, esters, phenols, and aliphatic, while inhibiting the production of aromatic and multi-hybrid compounds. Otherwise, there was no obvious interaction effect between hemi-cellulose and lignin or between lignin and protein. This research will guide the industrialization of lignocellulose, especially the possible co-feed hydro-thermal conversion technology.
引用
收藏
页数：11
相关论文
共 50 条
[31]   Combination of acid washing and torrefaction on Co-production of syngas and phenoli-riched bio-oil via low-temperature catalytic pyrolysis [J].
Su, Yinhai ;
Zhang, Shuping ;
Liu, Lingqin ;
Xu, Dan ;
Qi, Penggang ;
Xiong, Yuanquan .
ENERGY, 2020, 210
[32]   Effects of temperature and urea concentration on nitrogen-rich pyrolysis: Pyrolysis behavior and product distribution in bio-oil [J].
Liu, Shanjian ;
Zhao, An ;
He, Zhisen ;
Li, Yongjun ;
Bi, Dongmei ;
Gao, Xin .
ENERGY, 2022, 239
[33]   Catalytic co-pyrolysis of waste tobacco stem and corn stalk to produce bio-oil with low nitrogen/oxygen [J].
Bai, Jing ;
Yang, Luying ;
Wang, Yanhui ;
Huang, Guilin ;
Qiu, Chenxu ;
Sun, Zihui ;
Wu, Haoran ;
Chang, Chun .
FUEL, 2025, 395
[34]   Bio-oil and bio-char from low temperature pyrolysis of spent grains using activated alumina [J].
Sanna, Aimaro ;
Li, Sujing ;
Linforth, Rob ;
Smart, Katherine A. ;
Andresen, John M. .
BIORESOURCE TECHNOLOGY, 2011, 102 (22) :10695-10703
[35]   Green solvent-assisted hydrothermal conversion of biomass waste into bio-oil under pressurized conditions [J].
Bispo, Diego Fonseca ;
Loeser, Thiago Ferreira Leao ;
Cardozo-Filho, Lucio ;
Romero, Romina ;
Alejandro-Martin, Serguei ;
Jegatheesan, Jega ;
Freitas, Lisiane dos Santos .
BIOMASS CONVERSION AND BIOREFINERY, 2025, 15 (02) :2949-2961
[36]   Effect of low-temperature hydrothermal treatment of HZSM-5 extrudates on the production of deeply-deoxygenated bio-oil via ex-situ catalytic fast pyrolysis of biomass [J].
Promsampao, Nuttapan ;
Chollacoop, Nuwong ;
Pattiya, Adisak .
FUEL, 2022, 324
[37]   Effect of Ni/Al2O3 mixing on the coking behavior of bio-oil during its pyrolysis: Further understanding based on the interaction between its components [J].
Deng, Zengtong ;
Syed-Hassan, Syed Shatir A. ;
Chen, Yuanjing ;
Jiang, Long ;
Xu, Jun ;
Hu, Song ;
Su, Sheng ;
Wang, Yi ;
Xiang, Jun .
FUEL, 2022, 315
[38]   Hydrogen production by low-temperature reforming of organic compounds in bio-oil over a CNT-promoting Ni catalyst [J].
Hou, Tao ;
Yuan, Lixia ;
Ye, Tongqi ;
Gong, Lu ;
Tu, Jing ;
Yamamoto, Mitsuo ;
Torimoto, Youshifumi ;
Li, Quanxin .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (22) :9095-9107
[39]   Study on the hydrocarbon-rich bio-oil from catalytic fast co-pyrolysis cotton stalk and polypropylene over alkali-modified HZSM-5 [J].
Li, Zhaoying ;
Shi, Langqi ;
Liang, Daokuan ;
Li, Feixing ;
Wei, Lianghuan ;
Li, Weizun ;
Zha, Xianghao .
INDUSTRIAL CROPS AND PRODUCTS, 2025, 224
[40]   Shear property, high-temperature rheological performance and low-temperature flexibility of asphalt mastics modified with bio-oil [J].
Lei, Yong ;
Wang, Hainian ;
Chen, Xi ;
Yang, Xu ;
You, Zhanping ;
Dong, Shi ;
Gao, Junfeng .
CONSTRUCTION AND BUILDING MATERIALS, 2018, 174 :30-37
12345