Reduction of ketones to corresponding alcohols with magnesium metal in absolute alcohols

被引:7
作者
Kim, JY
Kim, HD
Seo, MJ
Kim, HR
No, Z
Ha, DC
Lee, GH
机构
[1] Korea Res Inst Chem Technol, Taejon 305600, South Korea
[2] Korea Univ, Dept Chem, Seoul 136701, South Korea
关键词
D O I
10.1016/j.tetlet.2005.10.140
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Various aliphatic and aromatic ketones are treated with 10 equiv of magnesium metal in absolute methanol or ethanol to afford corresponding alcohols in very high yields at room temperature within 12 h. (c) 2005 Published by Elsevier Ltd.
引用
收藏
页码:9 / 12
页数:4
相关论文
共 47 条
[21]   SELECTIVE CYCLOALKANONE REDUCTIONS USING ALUMINUM AMALGAM [J].
HULCE, M ;
LAVAUTE, T .
TETRAHEDRON LETTERS, 1988, 29 (05) :525-528
[22]   REDUCTIVE COUPLING OF CARBONYL-COMPOUNDS TO PINACOLS BY USING LOW-VALENT CERIUM [J].
IMAMOTO, T ;
KUSUMOTO, T ;
HATANAKA, Y ;
YOKOYAMA, M .
TETRAHEDRON LETTERS, 1982, 23 (13) :1353-1356
[23]  
KAGAN HB, 1981, TETRAHEDRON S, V9, P269
[24]  
KINAST G, 1967, CHEM BER, V109, P3626
[25]   METALS INTERCALATED IN GRAPHITE .1. REDUCTION AND OXIDATION [J].
LALANCETTE, JM ;
ROLLIN, G ;
DUMAS, P .
CANADIAN JOURNAL OF CHEMISTRY-BACK YEAR, 1972, 50 (18) :3058-+
[26]   REDUCTIVE CYCLIZATION OF KETONES TETHERED TO ACTIVATED OLEFINS MEDIATED BY MAGNESIUM IN METHANOL [J].
LEE, GH ;
CHOI, EB ;
LEE, E ;
PAK, CS .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (06) :1428-1443
[27]   Magnesium in methanol (Mg/MeOH) in organic syntheses [J].
Lee, GH ;
Youn, IK ;
Choi, EB ;
Lee, HK ;
Yon, GH ;
Yang, HC ;
Pak, CS .
CURRENT ORGANIC CHEMISTRY, 2004, 8 (13) :1263-1287
[28]  
LEE GH, 1995, TETRAHEDRON LETT, V36, P5607
[29]  
LEE GH, 1993, TETRAHEDRON LETT, V34, P4541
[30]   PREPARATION AND REACTIONS OF 11-SUBSTITUTED 1,3,5(10)-ESTRATRIENES .1. 11-OXYGENATED ESTRONES AND ESTRADIOLS [J].
MAGERLEIN, BJ ;
HOGG, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (09) :2220-2225