Reduction of ketones to corresponding alcohols with magnesium metal in absolute alcohols

被引：7
作者：
Kim, JY
Kim, HD
Seo, MJ
Kim, HR
No, Z
Ha, DC
Lee, GH
机构：
[1] Korea Res Inst Chem Technol, Taejon 305600, South Korea
[2] Korea Univ, Dept Chem, Seoul 136701, South Korea
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 01期
关键词：
D O I：
10.1016/j.tetlet.2005.10.140
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various aliphatic and aromatic ketones are treated with 10 equiv of magnesium metal in absolute methanol or ethanol to afford corresponding alcohols in very high yields at room temperature within 12 h. (c) 2005 Published by Elsevier Ltd.
引用
收藏
页码：9 / 12
页数：4
相关论文
共 47 条
[1]   REACTIONS OF POTASSIUM-GRAPHITE [J].
BERGBREITER, DE ;
KILLOUGH, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) :2126-2134
[2]  
CLARKE HT, 1944, ORG SYNTH, V1, P304
[3]   SOLVENT EFFECT IN THE REDUCTION OF ALPHA-KETO ESTERS BY AQUEOUS TITANIUM TRICHLORIDE [J].
CLERICI, A ;
PORTA, O .
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (23) :5099-5104
[4]   RADICAL-ADDITION TO THE CARBONYL CARBON OF KETONES PROMOTED BY AQUEOS TITANIUM TRICHLORIDE IN ACIDIC MEDIUM, ONE-STEP SYNTHESIS OF PINACOLS AND LACTONES [J].
CLERICI, A ;
PORTA, O ;
ZAGO, P .
TETRAHEDRON, 1986, 42 (02) :561-572
[5]   REDUCTION OF AROMATIC CARBONYL-COMPOUNDS PROMOTED BY TITANIUM TRICHLORIDE IN BASIC-MEDIA - STEREOCHEMISTRY STUDIES [J].
CLERICI, A ;
PORTA, O .
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (01) :76-81
[6]   RING-OPENING OF CYCLOPROPYLKETONES INDUCED BY PHOTOCHEMICAL ELECTRON-TRANSFER [J].
COSSY, J ;
FURET, N ;
BOUZBOUZ, S .
TETRAHEDRON, 1995, 51 (43) :11751-11764
[7]   STUDIES IN STEREOCHEMISTRY .36. RADICAL ANIONS AS NEIGHBORING AND ELECTRON TRANSFER GROUPS IN SUBSTITUTION-REDUCTION REACTIONS [J].
CRAM, DJ ;
DALTON, CK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (09) :1268-&
[8]  
DEV S, 1956, J INDIAN CHEM SOC, V33, P769
[9]   NUCLEAR MAGNETIC RESONANCE SPECTRA AND STEREOCHEMISTRY OF SUBSTITUTED BORNANES [J].
FLAUTT, TJ ;
ERMAN, WF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (20) :3212-&
[10]   BAKERS-YEAST REDUCTION OF ARYLIDENECYCLOALKANONES [J].
FOGLIATO, G ;
FRONZA, G ;
FUGANTI, C ;
LANATI, S ;
RALLO, R ;
RIGONI, R ;
SERVI, S .
TETRAHEDRON, 1995, 51 (37) :10231-10240
12345