Transition-Metal-Catalyzed Hydroaminocarbonylations of Alkenes and Alkynes

被引：64

作者：

Cai, Shoule ^{[1
,2
]}

Zhang, Haocheng ^{[1
,2
]}

Huang, Hanmin ^{[1
,2
,3
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[3] Chinese Acad Sci, Ctr Excellence Mol Synth, Hefei 230026, Peoples R China

来源：

TRENDS IN CHEMISTRY | 2021年 / 3卷 / 03期

基金：

中国国家自然科学基金;

关键词：

REGIOSELECTIVE SYNTHESIS; AMINOCARBONYLATION; OLEFINS; CYCLOCARBONYLATION; CARBONYLATION; AMINES; BONDS; AMIDE; HYDROAMIDOCARBONYLATION; PALLADIUM(II);

D O I：

10.1016/j.trechm.2020.11.006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

While the amide bond is one of the most widespread backbones in natural peptides, pharmaceuticals, and agrochemicals, the atom-economic synthesis of amides remains a major challenge in organic chemistry. In this context, transition-metal-catalyzed hydroaminocarbonylation of cost-effective alkenes and alkynes has emerged as an ideal approach to access amides. However, it is only in recent times that more chemo- and regioselective hydroaminocarbonylation transformations, covering large substrate scope and under milder conditions, have been reported. In this review, we highlight some recent contributions to this field and elucidate the impact of ligands on regioselectivity, as well as discuss the potential applications of abundantly available nitrogen sources for hydroaminocarbonylation.

引用

收藏

页码：218 / 230

页数：13

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