Sympathetic current oscillations at an enzyme electrode induced by potential oscillations at a Pt surface

被引:1
|
作者
Wilson, Benjamin P. [1 ]
Yliniemi, Kirsi [1 ]
Murtomaki, Lasse [1 ]
Kontturi, Kyosti [1 ]
机构
[1] Helsinki Univ Technol TKK, Dept Chem, Phys Chem & Electrochem Lab, FI-02015 Espoo, Finland
关键词
Oscillations; Glucose oxidase; Ferricyanide; GLUCOSE-OXIDASE; REDUCTION; CATALASE; ANIONS;
D O I
10.1016/j.elecom.2009.10.022
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A dual-electrode set-up is introduced in order to demonstrate that electrochemical oscillations at one electrode can induce sympathetic oscillations at the other electrode. A pure Pt surface is used as a primary electrode at which the potential oscillations of the [Fe(CN)(6)](3-) system with convective feedback occur and stimulate current oscillations at a Pt or glucose oxidase enzyme (GOD) + tetraethyl silicate (TEOS) coated electrode placed in the vicinity. The current density of the primary electrode and glucose concentration can be used to influence the frequency and amplitude of oscillations at the GOD + TEOS electrode. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2328 / 2331
页数:4
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