New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates

被引：14
|
作者：
Zhdanov, A. P. [1 ,2 ]
Voinova, V. V. [1 ,2 ]
Klyukin, I. N. [1 ]
Kubasov, A. S. [1 ]
Zhizhin, K. Yu. [1 ]
Kuznetsov, N. T. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 117907, Russia
[2] Lobachevsky State Univ Nizhni Novgorod, Gagarina Pr 23, Nizhnii Novgorod 603950, Russia
来源：
JOURNAL OF CLUSTER SCIENCE | 2019年 / 30卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
Nitrilium derivative; Boron cluster; Closo-decaborate; Reduction process; NITRILIUM DERIVATIVES; NUCLEOPHILIC-ADDITION; CRYSTAL-STRUCTURES; ANION; ASTATINATION; REACTIVITY; REAGENTS; NITROGEN; CLOSO-DECABORATE(2-); POLYAMINOBORANES;
D O I：
10.1007/s10876-019-01628-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In work, the process of interaction of nitrilium derivatives of the closo-decaborate anion with lithium aluminum hydride was studied. Reduction process proceeds under mild conditions and leads to the formation of N-alkylammonium-closo-decaborate with high yields and selectivity. For the structure of ((NBu4)-Bu-n)[2-B10H(9)NH(2)CH(2)CH(3)] was confirmed by single-crystal X-ray diffraction.
引用
收藏
页码：1327 / 1333
页数：7
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