New Synthesis Method of N-Monosubstituted Ammonium-closo-Decaborates

被引：14

作者：

Zhdanov, A. P. ^{[1
,2
]}

Voinova, V. V. ^{[1
,2
]}

Klyukin, I. N. ^{[1
]}

Kubasov, A. S. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 117907, Russia

[2] Lobachevsky State Univ Nizhni Novgorod, Gagarina Pr 23, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF CLUSTER SCIENCE | 2019年 / 30卷 / 05期

基金：

俄罗斯科学基金会;

关键词：

Nitrilium derivative; Boron cluster; Closo-decaborate; Reduction process; NITRILIUM DERIVATIVES; NUCLEOPHILIC-ADDITION; CRYSTAL-STRUCTURES; ANION; ASTATINATION; REACTIVITY; REAGENTS; NITROGEN; CLOSO-DECABORATE(2-); POLYAMINOBORANES;

D O I：

10.1007/s10876-019-01628-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In work, the process of interaction of nitrilium derivatives of the closo-decaborate anion with lithium aluminum hydride was studied. Reduction process proceeds under mild conditions and leads to the formation of N-alkylammonium-closo-decaborate with high yields and selectivity. For the structure of ((NBu4)-Bu-n)[2-B10H(9)NH(2)CH(2)CH(3)] was confirmed by single-crystal X-ray diffraction.

引用

页码：1327 / 1333

页数：7

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