Structure of a phenylacetylene macrocycle at the air-water interface

被引：16

作者：

Mindyuk, OY

Stetzer, MR

Gidalevitz, D

Heiney, PA ^{[1
]}

Nelson, JC

Moore, JS

机构：

[1] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA

[2] Univ Penn, Res Struct Matter Lab, Philadelphia, PA 19104 USA

[3] Univ Illinois, Dept Chem, Roger Adams Lab, Urbana, IL 61801 USA

[4] Univ Illinois, Roger Adams Lab, Dept Engn, Urbana, IL 61801 USA

来源：

LANGMUIR | 1999年 / 15卷 / 20期

关键词：

D O I：

10.1021/la981092x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have used grazing incidence X-ray diffraction and X-ray specular reflectivity to study Langmuir films of a phenylacetylene macrocycle (PAM), a ring-shaped molecule known to form a tubular liquid crystal. PAM adopts an "edge-on" molecular arrangement at the air-water interface. The local structure is quite similar to that of the corresponding bulk columnar liquid crystal, but with enhanced order in the intracolumnar direction. The columnar order is disrupted by CsCl in the subphase and strongly enhanced by KCl in the subphase.

引用

页码：6897 / 6900

页数：4

共 50 条

[1] Assembly of amphiphilic phenylacetylene macrocycles at the air-water interface and on solid surfaces
J Am Chem Soc, 39 (9409):
[2] Assembly of amphiphilic phenylacetylene macrocycles at the air-water interface and on solid surfaces
Shetty, AS
Fischer, PR
Stork, KF
Bohn, PW
Moore, JS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (39) : 9409 - 9414
[3] The Macrocycle Plane Orientation of Phthalocyanine and Porphyrin Derivatives on an Air-water Interface
Xiao, Hai-Xia
Cheng, Xu-Xin
Xi, Shi-Quan
Cui, Hai-Ning
PROCEEDINGS OF THE 2016 INTERNATIONAL FORUM ON ENERGY, ENVIRONMENT AND SUSTAINABLE DEVELOPMENT (IFEESD), 2016, 75 : 550 - 554
[4] The structure of mixed surfactants at the air-water interface
Penfold, J
Staples, EJ
Tucker, I
Thomas, RK
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 155 (01) : 11 - 26
[5] Structure and denaturation of adsorbed lysozyme at the air-water interface
Postel, C
Abillon, O
Desbat, B
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 266 (01) : 74 - 81
[6] Structure and dynamics of hydrogen bonds at the air-water interface
Benderskii, Alexander V.
Vinaykin, Mikhail
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
[7] Structure and organization of alcohol monolayers at the air-water interface
Mago, Deesha D.
Can, Suleyman Z.
Walker, Robert A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 415 - 415
[8] Structure of dense polymer brushes at the air-water interface
Bianco-Peled, H
Dori, Y
Scheider, J
Tirrell, M
Sung, LP
Satija, S
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U767 - U767
[9] Sphingomyelin at the air-water interface
Vaknin, D
Kelley, MS
Ocko, BM
JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (16): : 7697 - 7704
[10] ON INSTABILITY OF AN AIR-WATER INTERFACE
GANGADHA.T
RAO, NSL
SEETHARA.K
INDIAN JOURNAL OF TECHNOLOGY, 1970, 8 (04): : 120 - &

← 1 2 3 4 5 →