Light-assisted O-methylation of phenol with dimethyl carbonate over a layered double oxide catalyst

被引：14

作者：

Wang, Xiaoyu ^{[1
,2
]}

Wang, Ruiyi ^{[1
]}

Gu, Xianmo ^{[1
]}

Jia, Jianfeng ^{[3
]}

Zheng, Zhanfeng ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China

[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China

[3] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2019年 / 9卷 / 08期

基金：

中国国家自然科学基金;

关键词：

CALCINED MG-AL; DOUBLE HYDROXIDES; ALKYLATION; ETHERS; HYDROTALCITE; CONDENSATION; BASICITY;

D O I：

10.1039/c8cy02579g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Layered double oxides (LDOs) exhibit high catalytic activity in the O-methylation of phenol under light irradiation, owing to the synergy of the light absorption of phenol molecules to achieve excited states and the facilitated adsorption of reactant molecules by the acid-base pairs of Mg3Al-LDO, both of which can promote phenol deprotonation.

引用

页码：1774 / 1778

页数：5

共 19 条

[1] Selective O-Methylation of Phenol with Dimethyl Carbonate over Catalysts Supported on CaO
Zhang, Zhifang
Xu, Zhongying
Li, Shaoying
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KINETICS AND CATALYSIS, 2021, 62 (04) : 496 - 506
[2] Selectivity engineering of O-methylation of hydroxybenzenes with dimethyl carbonate using ionic liquid as catalyst
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Huuhtanen, Mika
Keiski, Riitta L.
Yadav, Ganapati D.
REACTION CHEMISTRY & ENGINEERING, 2016, 1 (03): : 330 - 339
[3] Efficient and Stable O-Methylation of Catechol with Dimethyl Carbonate over Aluminophosphate Catalysts
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Sheng, Yao
Zhou, Linkai
Hong, Runduo
Zhang, Lifan
Ren, Xinfeng
Zou, Xiujing
Shang, Xingfu
Lu, Xionggang
Wang, Xueguang
CATALYSTS, 2023, 13 (01)
[4] Magnesium oxide as a heterogeneous and recyclable base for the N-methylation of indole and O-methylation of phenol using dimethyl carbonate as a green methylating agent
Gadge, Sandip T.
Mishra, Ashish
Gajengi, Aravind L.
Shahi, Nileshkumar V.
Bhanage, Bhalchandra M.
RSC ADVANCES, 2014, 4 (91) : 50271 - 50276
[5] Catechol O-methylation with dimethyl carbonate over different acid-base catalysts
Luque, Rafael
Campelo, Juan Manuel
Conesa, Tomas David
Luna, Diego
Marinas, Jose Maria
Romero, Antonio Angel
NEW JOURNAL OF CHEMISTRY, 2006, 30 (08) : 1228 - 1234
[6] Fluorine-modified mesoporous Mg-Al mixed oxides:: Mild and stable base catalysts for O-methylation of phenol with dimethyl carbonate
Wu, Gongde
Wang, Xiaoli
Chen, Bing
Li, Junping
Zhao, Ning
Wei, Wei
Sun, Yuhan
APPLIED CATALYSIS A-GENERAL, 2007, 329 : 106 - 111
[7] O-Methylation of the Phenolic Bio-oil with Dimethyl Carbonate in an Ionic Liquid [bmim]Cl
Nie, Jun-Qi
Chen, Hong-Wei
Song, Qin-Hua
Liao, Bing
Guo, Qing-Xiang
ENERGY & FUELS, 2010, 24 (10) : 5722 - 5726
[8] Selectivity engineering of solid base catalyzed O-methylation of 2-naphthol with dimethyl carbonate to 2-methoxynaphthalene
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Salunke, Jeetendra Y.
CATALYSIS TODAY, 2013, 207 : 180 - 190
[9] Amino acid intercalated layered double hydroxide catalyzed chemoselective methylation of phenols and thiophenols with dimethyl carbonate
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Dhakshinamoorthy, Amarajothi
Pitchumani, Kasi
TETRAHEDRON LETTERS, 2013, 54 (52) : 7167 - 7170
[10] Synthesis of Glycerol Carbonate by Transesterification of Glycerol and Dimethyl Carbonate over KF/γ-Al2O3 Catalyst
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Wang, Junwei
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Yin, Ning
Wang, Xinkui
Tan, Yisheng
Zhu, Yulei
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2014, 25 (01) : 152 - 160

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