Synthesis and optical properties of new 2-(5-arylpyridine-2-yl)-6-(het) arylquinoline-based "push-pull" fluorophores

被引:13
作者
Kopchuka, Dmitry S. [1 ,2 ]
Chepchugov, Nikolay, V [1 ]
Starnovskaya, Ekaterina S. [1 ,2 ]
Khasanova, Albert F. [1 ,2 ]
Krinochkin, Alexey P. [1 ,2 ]
Santra, Sougata [1 ]
Zyryanov, Grigory, V [1 ,2 ]
Das, Pralay [3 ,4 ]
Majee, Adinath [5 ]
Rusinov, Vladimir L. [1 ,2 ]
Charushin, Valery N. [1 ,2 ]
机构
[1] Ural Fed Univ, Chem Engn Inst, Dept Organ & Biomol Chem, 19 Mira St, Ekaterinburg 62000, Russia
[2] RAS, Ural Div, I Ya Postovsky Inst Organ Synth, 22-20 S Kovalevskoy,Akad Skaya St, Ekaterinburg 62099, Russia
[3] CSIR Inst Himalayan Bioresource Technol, Nat Prod Chem & Proc Dev, Palampur 176061, Himachal Prades, India
[4] Acad Sci & Innovat Res AcSIR, New Delhi, India
[5] Visva Bharati, Dept Chem, Santini Ketan 731235, W Bengal, India
基金
俄罗斯科学基金会;
关键词
2-(5-arylpyridine-2-yl)-6-(het)arylquinoline; Push-pull" fluorophores; 1,2,4-Triazine method; Optical properties; Solvatochromic properties; Data analysis; HMG-COA REDUCTASE; PHOTOPHYSICAL PROPERTIES; CHARGE-TRANSFER; QUANTUM YIELDS; WATER; FLUORESCENCE; COMPLEXES; OXIDATION; DYES; QUINOLINE;
D O I
10.1016/j.dyepig.2019.04.029
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
2-(5-Arylpyridine-2-y1)-6-(het)arylquinoline-based "push-pull" fluorophores were synthesized by means of the heterocyclization reaction between the corresponding isonitrosoacetophenone hydrazones and 6-bromoquinoline-2-carboxaldehyde followed by an aza-Diels-Alder/Suzuki cross-coupling reaction sequence. The optical properties of the obtained fluorophores were studied and the non-linear optic behavior for the two most representative ones were confirmed based on the solvatochromic experiments.
引用
收藏
页码:151 / 156
页数:6
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