Sustainable routes to polyurethane precursors

被引：341

作者：

Kreye, Oliver ^{[1
]}

Mutlu, Hatice ^{[1
]}

Meier, Michael A. R. ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Organ Chem, D-76131 Karlsruhe, Germany

来源：

GREEN CHEMISTRY | 2013年 / 15卷 / 06期

关键词：

CATALYZED REDUCTIVE CARBONYLATION; ONE-POT SYNTHESIS; RING-OPENING POLYMERIZATION; NICKEL(0)-CATALYZED CYCLOADDITION COPOLYMERIZATION; AROMATIC NITRO-COMPOUNDS; REGIOSELECTIVE ENZYMATIC ALKOXYCARBONYLATION; PHASE OXIDATIVE CARBONYLATION; N-TERT-BUTYLOXYCARBONYLATION; PRIMARY ALIPHATIC-AMINES; PHOSGENE-FREE SYNTHESIS;

D O I：

10.1039/c3gc40440d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Environmentally friendly products and procedures are being developed both in industry and academia, mainly due to the depletion of fossil resources and the growing global awareness of the need to protect the environment. Thus, since polyurethanes represent a highly demanded class of polymers, straightforward, isocyanate and phosgene-free methods are required for the synthesis of their precursors (monomers) in order to achieve a sustainable production. To foster the discussion with the final goal to meet such a sustainable production, this review provides an overview of classic as well as modern and more sustainable routes towards polyurethanes and their precursors.

引用

页码：1431 / 1455

页数：25

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