Synthesis, structure and magnetic characterization of [Fe(bpp)2][Cu(pds)2]2•solv (solv = CH3CN and CH3OH)

被引：8

作者：

Coronado, Eugenio ^{[1
]}

Dias, Joao C. ^{[1
]}

Gimenez-Lopez, M. Carmen ^{[1
]}

Gimenez-Saiz, Carlos ^{[1
]}

Gomez-Garcia, Carlos J. ^{[1
]}

机构：

[1] Univ Valencia, ICMol, Poligono Coma S-N, E-46980 Paterna, Spain

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2008年 / 890卷 / 1-3期

关键词：

Magnetic properties; Spin crossover; Fe(II) complexes; Switchable molecular materials; Diselenolates; Molecular conductors;

D O I：

10.1016/j.molstruc.2008.04.046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel salt of the Fe(II) cation [Fe(bpp)(2)](2+) ( bpp = 2,6-bis(pyrazol-3-yl)pyridine) with the [Cu-III(pds)(2)](-) anion (pds = pirazine-2,3-diselenolate) formulated as [Fe(bpp)(2)][Cu(pds)(2)](2) center dot 3CH(3)CN has been prepared and characterized by single crystal X-ray diffraction and magnetic measurements. The salt presents a layered structure where cations and anions alternate along the b direction with many intermolecular short contacts between the cations and anions. The magnetic properties show that the Fe(II) cations [Fe(bpP)(2)](2+) present a high-spin S = 2 ground spin state with g = 2.073(1) and a zero field splitting (ZFS) of 7.7(1) cm(-1) but no the expected spin transition at low temperatures. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：215 / 220

页数：6

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