Comparative study of the reactivities of the components in the selective hydrogenation of the mixture C-2-C-3.

被引:0
作者
Seoane, CG
Cabanes, AL
Cano, GV
机构
关键词
hydrogenation; acetylene; methylacetylene; propadiene; tail end; front end;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The selective hydrogenation of the pyrolisis fraction C-2 in order to eliminate the existing acetone is a well known process. Nevertheless, it could be more interesting, from an industrial point of view, to make the hydrogenation not only of the C-2 but also of the C-3. In the present work, it is studied comparatively the level of hydrogenation of the most insaturated hydrocarbons of the fractions C-2 and C-3 in the mixture assembly C-2-C-3 or C-3-, and interesting results are found. It is also analyzed the acetylene hydrogenation in the fraction C-2 and in the amplified fraction C-2-G(3) and it is found that in some cases, the latter may offer some advantages. The study takes place considering the process versions known as tail end and front end, showing only a reduced number of results graphics, as an example.
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页码:379 / 386
页数:8
相关论文
共 13 条
  • [1] BOITIAUX JP, 1994, ERDOL KOHLE ERDGAS P, V47, P141
  • [2] CABANES AL, 1986, PIROLISIS HIDROCARBU
  • [3] CHAUVEL A, 1977, STEAM CRACKING
  • [4] Derrien M.L., 1986, Studies in Surface Science and Catalysis, V27, P613, DOI DOI 10.1016/S0167-2991(08)65364-1
  • [5] FAJARDO JC, 1994, ANAL CINETICO HIDROG
  • [6] GODINEZ C, 1983, INGENIERIA QUIMICA, V297, P65
  • [7] Guisnet M., 1988, Stud. Surf. Sci. Catal, V41, P145
  • [8] KUMMEROW I, 1983, CHEM ENG TODAY, P103
  • [9] LEPRINCE P, 1971, PROCEDES PETROCHIMIE
  • [10] STRUCTURAL ASPECTS OF THE LINDLAR CATALYST FOR SELECTIVE HYDROGENATION
    Stachurski, Jaroslaw
    Thomas, John M.
    [J]. CATALYSIS LETTERS, 1988, 1 (1-3) : 67 - 72