Facile synthesis of heterotrimetallic metal-string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

被引：32
|
作者：
Cheng, Ming-Chuan [1 ,2 ]
Mai, Chi-Lun [3 ]
Yeh, Chen-Yu [3 ]
Lee, Gene-Hsiang [1 ]
Peng, Shie-Ming [1 ,2 ]
机构：
[1] Natl Taipei Univ Technol, Dept Chem, Taipei 106, Taiwan
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[3] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 72期
关键词：
LOW-SYMMETRY DISTORTIONS; ATOM CHAINS; ELECTRON-TRANSPORT; LIGANDS; CONDUCTANCE; BONDS;
D O I：
10.1039/c3cc43909g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This communication provides a practical strategy for the synthesis of heterotrimetallic extended metal atom chains with supported dpa(-) ligands. The transformation of the CoCoRh to a NiCoRh trinuclear complex can be achieved by direct metallic replacement. Furthermore, the first (CoRh)(4+) metal-metal bond is described here.
引用
收藏
页码：7938 / 7940
页数：3
相关论文
共 16 条
  • [1] Effects of Electric Field on the Structures of Metal String Complexes M3(dpa)4Cl2 (M=Co, Rh, Ir; dpa=dipyridylamide)
    Huang Yan
    Huang Xiao
    Xu Xuan
    ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (06) : 1225 - 1232
  • [2] Synthesis, Structure, and Cyclic Voltammetric Property of Metal String Complex [Ni3(dpa)4(ClO4)(Cl)]•CH2Cl2
    Miao, Xiao-He
    Zhu, Long-Guan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (05): : 878 - 881
  • [3] Completing the series of Group VI heterotrimetallic M2Cr(dpa)4Cl2 (M2 = Cr2, Mo2, MoW and W2) compounds and investigating their metal-metal interactions using density functional theory
    Brogden, David W.
    Christian, Jonathan H.
    Dalal, Naresh S.
    Berry, John F.
    INORGANICA CHIMICA ACTA, 2015, 424 : 241 - 247
  • [4] Electronic Transport Properties of Asymmetric Metal String Complex [Cu2Pt(npa)4X2](X=Cl-, NCS-)
    Zhou Wohua
    Chen Rong
    Wu Ziwen
    Ding Dandan
    Xu Zhiguang
    Xu Xuan
    Luo Yifan
    ACTA CHIMICA SINICA, 2015, 73 (11) : 1214 - 1218
  • [5] Coordination Structures of Metal String Complexes (n, m)[Cr3(PhPyF)4Cl2](n=2, 3, 4; m=2, 1, 0) and Relationship with External Electric Field
    Ding Dan-Dan
    Xu Xuan
    Wu Zi-Wen
    Zhou Wo-Hua
    Chen Rong
    Xu Zhi-Guang
    ACTA PHYSICO-CHIMICA SINICA, 2015, 31 (07) : 1323 - 1330
  • [6] Excited-State Dynamics of the Metal String Complex Co3(dpa)4(NCS)2 from Femtosecond Transient Absorption Spectra
    Cheng, Chao-Han
    Hung, Ruei-Ding
    Wang, Wen-Zhen
    Peng, Shie-Ming
    Chen, I-Chia
    CHEMPHYSCHEM, 2010, 11 (02) : 466 - 473
  • [7] Excited-State Dynamics of Metal String Complex Ni3(dpa)4X2 from Femtosecond Transient Absorption Spectra
    Cheng, Chao-Han
    Hung, Ruei-Ding
    Wang, Wen-Zhen
    Peng, Shie-Ming
    Chen, I-Chia
    CHEMPHYSCHEM, 2010, 11 (02) : 517 - 524
  • [8] Theoretical Studies on the Structures of Metal String Complexes Crn(L)4Cl2 (n=3, 5, 7; L = Oligo-α-Pyridylamide) under the Effect of an Electric Field
    Gao, Pan
    Cai, Xue-Ping
    Xie, Qiongyi
    Yang, Qingyun
    Ou, Hong
    Wu, Wei-Qing
    Xu, Xuan
    Xu, Zhiguang
    Lin, Xiaoming
    INORGANIC CHEMISTRY, 2021, 60 (13) : 9378 - 9386
  • [9] Facile synthesis of a novel tetrazole Schiff base complex of CoIII via [3+2] cycloaddition of metal coordinated azid with cyanopyridine
    Das, Mithun
    Chattopadhyay, Shouvik
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2015, 92 (08) : 1191 - 1197
  • [10] Periodic trends in electron transport through extended metal atom chains: comparison of Ru3(dpa)4(NCS)2 with its first-row analogues
    Mohan, P. J.
    Georgiev, Vihar P.
    McGrady, John E.
    CHEMICAL SCIENCE, 2012, 3 (04) : 1319 - 1329
12